Generalized reactivity descriptor of defective carbon catalysts for acetylene hydrochlorination: the ratio of sp2 : sp3 hybridization

被引：30

作者：

Qiu, Yiyang ^{[1
]}

Fan, Dong ^{[2
]}

Lan, Guojun ^{[1
]}

Wei, Shuhao ^{[1
]}

Hu, Xiaojun ^{[2
]}

Li, Ying ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Inst Ind Catalysis, ChaoWang Rd 18, Hangzhou 310032, Peoples R China

[2] Zhejiang Univ Technol, Coll Mat & Sci, Address 18 Chaowang Rd, Hangzhou 310014, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 94期

关键词：

Acetylene; -; Nanocatalysts; Lighting;

D O I：

10.1039/d0cc06177h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The golden section point in carbon catalysts for acetylene hydrochlorination has been determined. The surface sp(2) : sp(3) ratio of two types of carbon catalysts, including nanodiamond- and graphite-oriented carbons, both have a volcano relationship with the catalytic performance for acetylene hydrochlorination, and the optimized ratios are both around 32-35%.

引用

页码：14877 / 14880

页数：4

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