Synthesis of nanosized mesoporous silicon by magnesium-thermal method used as anode material for lithium ion battery

被引:48
作者
Zhong, Hai [1 ]
Zhan, Hui [1 ]
Zhou, Yun-Hong [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
关键词
Magnesium thermal reduction; Nanosized mesoporous silicon; Silica; Anode material; Lithium ion battery; NANOCOMPOSITE; ELECTRODES; CAPACITY; SI;
D O I
10.1016/j.jpowsour.2014.03.108
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Magnesium thermal reduction of the silica aggregation following with HF etching is used to obtain mesoporous nano-Silicon. The product shows an 1844 mAh g(-1) discharge capacity in the first cycle with 400 mA g(-1) current density and it still delivers a 1444 mAh g(-1) capacity after 100 cycles. Additionally, it presents a good rate capability. The mesoporous morphology and the ultra-fine particle are the reasons of the good electrochemical property. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:10 / 14
页数:5
相关论文
共 18 条
[1]   High-performance lithium battery anodes using silicon nanowires [J].
Chan, Candace K. ;
Peng, Hailin ;
Liu, Gao ;
McIlwrath, Kevin ;
Zhang, Xiao Feng ;
Huggins, Robert A. ;
Cui, Yi .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35
[2]   Mesoporous Silicon Anodes Prepared by Magnesiothermic Reduction for Lithium Ion Batteries [J].
Chen, Wei ;
Fan, Zhongli ;
Dhanabalan, Abirami ;
Chen, Chunhui ;
Wang, Chunlei .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (09) :A1055-A1059
[3]   Enhanced reversible lithium storage in a nanosize silicon/graphene composite [J].
Chou, Shu-Lei ;
Wang, Jia-Zhao ;
Choucair, Mohammad ;
Liu, Hua-Kun ;
Stride, John A. ;
Dou, Shi-Xue .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (02) :303-306
[4]   A porous silicon-carbon anode with high overall capacity on carbon fiber current collector [J].
Guo, Juchen ;
Sun, Ann ;
Wang, Chunsheng .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (07) :981-984
[5]   A polymer scaffold binder structure for high capacity silicon anode of lithium-ion battery [J].
Guo, Juchen ;
Wang, Chunsheng .
CHEMICAL COMMUNICATIONS, 2010, 46 (09) :1428-1430
[6]   Lithium insertion in Si-TiC nanocomposite materials produced by high-energy mechanical milling [J].
Guo, ZP ;
Zhao, ZW ;
Liu, HK ;
Dou, SX .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :190-194
[7]   Amorphous silicon anode for lithium-ion rechargeable batteries [J].
Jung, HJ ;
Park, M ;
Yoon, YG ;
Kim, GB ;
Joo, SK .
JOURNAL OF POWER SOURCES, 2003, 115 (02) :346-351
[8]   An in situ X-ray diffraction study of the reaction of Li with crystalline Si [J].
Li, Jing ;
Dahn, J. R. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (03) :A156-A161
[9]   Silicon Nanotube Battery Anodes [J].
Park, Mi-Hee ;
Kim, Min Gyu ;
Joo, Jaebum ;
Kim, Kitae ;
Kim, Jeyoung ;
Ahn, Soonho ;
Cui, Yi ;
Cho, Jaephil .
NANO LETTERS, 2009, 9 (11) :3844-3847
[10]   Study of lithiation mechanisms in silicon electrodes by Auger Electron Spectroscopy [J].
Radvanyi, Etienne ;
De Vito, Eric ;
Porcher, Willy ;
Danet, Julien ;
Desbois, Philippe ;
Colin, Jean-Francois ;
Larbi, Severine Jouanneau Si .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (16) :4956-4965