Acid doped polybenzimidazoles based membrane electrode assembly for high temperature proton exchange membrane fuel cell: A review

被引：115

作者：

Haque, M. Ahsanul ^{[1
,2
]}

Sulong, A. B. ^{[1
,3
]}

Loh, K. S. ^{[1
]}

Majlan, E. Herianto ^{[1
]}

Husaini, T. ^{[1
]}

Rosli, R. Emilia ^{[1
]}

机构：

[1] Univ Kebangsaan Malaysia, Fuel Cell Inst, Ukm Bangi Selangor 43600, Malaysia

[2] Islamic Univ, Dept Appl Chem & Chem Technol, Kushtia 7003, Bangladesh

[3] Univ Kebangsaan Malaysia, Dept Mech & Mat Engn, Bangi Selangor 43600, Malaysia

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2017年 / 42卷 / 14期

关键词：

Acid doping; High temperature; Polybenzimidazole; Membrane electrode assembly and durability; MULTIWALLED CARBON NANOTUBES; POLYMER ELECTROLYTE; PHOSPHORIC-ACID; OXYGEN REDUCTION; CATHODE CATALYST; COMPOSITE MEMBRANES; SUPPORTED PLATINUM; IONOMER MEMBRANES; SURFACE-AREA; POLY(2,5-BENZIMIDAZOLE) ABPBI;

D O I：

10.1016/j.ijhydene.2016.03.086

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

High temperature proton exchange membrane fuel cells (HT-PEMFCs) are proficient clean energy conversion devices for automotive and stationary applications. HT-PEMFC could mitigate the CO poisoning, humidity and heat management, and sluggish of oxygen reduction reaction (ORR). Acid doped polybenzimidazoles (PBIs)/functionalized PBIs polymer electrolyte membranes are familiar uses for HT-PEMFC because of high proton conductivity with thermo-mechanical stability. Proton conductivity of PBI membranes is greatly promising by acid doping dimension and cell operating temperature. FBI reactive sites (=N-H) and acidic anions prominently contribute the proton transfer through the prolonged hydrogen bonding network. Coating and sprayed methods are prominent techniques for fabrication of gas diffusion electrodes (GDEs), although shrinkage and hairline surface cracks observed on GDEs. Multi walled carbon nanotubes (MWCNTs) has been compromising unique characteristics for steady carbon support materials. Moreover, PTFE and PVDF can be used as catalyst binder to reduce corrosion rate. In this review, it has been focused the PBIs membrane, acid doping, GDEs, MEA and durability of MEA. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：9156 / 9179

页数：24

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