Unusual reactivity of lanthanide borohydride complexes leading to a borane complex

被引：38

作者：

Meyer, Nils ^{[2
]}

Jenter, Jelena ^{[1
]}

Roesky, Peter W. ^{[1
]}

Eickerling, Georg ^{[3
]}

Scherer, Wolfgang ^{[3
]}

机构：

[1] Univ Karlsruhe TH, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

[2] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

[3] Univ Augsburg, Inst Phys, D-86159 Augsburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 31期

关键词：

EPSILON-CAPROLACTONE POLYMERIZATION; STEREOSPECIFIC POLYMERIZATION; UNPRECEDENTED POLYMERIZATION; MECHANISTIC INSIGHTS; CRYSTAL-STRUCTURES; CATALYSTS; ISOPRENE; ETHYLENE; METAL; INITIATORS;

D O I：

10.1039/b907193h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Depending on the ionic radius of the central metal atom the BH4- group, which usually reacts in lanthanide chemistry like a pseudo halide, can be involved in redox chemistry and the resulting product contains an N-BH3 unit, which binds in an unusual eta(2)-fashion onto the metal atom.

引用

页码：4693 / 4695

页数：3

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