Synthesis and Electrochromic Characterization of the Graphene/Poly(ethylene oxide)/V2O5 • nH2O Ternary Nanocomposite Films

被引：7

作者：

Jiang, ShanShan ^{[1
]}

Li, Zhaolong ^{[1
]}

Huang, Shengnan ^{[1
]}

Lu, Shan ^{[1
]}

Yu, Yue ^{[1
]}

Mou, Guangying ^{[1
]}

Xu, Jie ^{[1
]}

Zhu, Quanyao ^{[1
]}

Tan, Xi ^{[1
]}

Zhu, XiangLe ^{[1
]}

Zakharova, Galina S. ^{[2
]}

机构：

[1] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China

[2] Russian Acad Sci, Inst Solid State Chem, Ural Branch, Ekaterinburg 620990, Russia

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2014年 / 161卷 / 10期

基金：

俄罗斯基础研究基金会; 中国国家自然科学基金;

关键词：

CORE-SHELL STRUCTURE; VANADIUM-OXIDE; FLEXIBLE ELECTRODES; SOL-GEL; PERFORMANCE; COMPOSITES; MULTICOLOR; DEPOSITION; NANOWIRES; NANOTUBES;

D O I：

10.1149/2.0991410jes

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The graphene/poly (ethylene oxide)/V2O5 center dot nH(2)O films (GPV) were fabricated by sal-gel method. The structure of the ternary nanocomposite films were investigated by X-Ray Diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). V2O5 center dot nH(2)O layered structure was intercalated by poly (ethylene oxide) (PEO) and graphene. The electrochemical properties of the nanocomposite films were measured by the cyclic voltammetry (CV) and chronoamperometry (CA) measurements with the standard three-electrode configuration. The optical properties were characterized by ultraviolet visible spectrophotometer. The electrochromic response rate of the GPV films is enhanced evidently. Its bleaching time is 1.8 second, and the coloration time is 3.8 second. These results demonstrate that the GPV films have a potential application in the fast switching electrochromic devices. (C) 2014 The Electrochemical Society. All rights reserved.

引用

页码：H684 / H688

页数：5

共 39 条

[1] Electron transport and full-band electron-phonon interactions in graphene [J].

Akturk, Akin ;

Goldsman, Neil .

JOURNAL OF APPLIED PHYSICS, 2008, 103 (05)

[2] Pd-Sensitized Single Vanadium Oxide Nanowires: Highly Responsive Hydrogen Sensing Based on the Metal-insulator Transition [J].

Baik, Jeong Min ;

Kim, Myung Hwa ;

Larson, Christopher ;

Yavuz, Cafer T. ;

Stucky, Galen D. ;

Wodtke, Alec M. ;

Moskovits, Martin .

NANO LETTERS, 2009, 9 (12) :3980-3984

[3] Synthesis of PEDOT-modified graphene composite materials as flexible electrodes for energy storage and conversion applications [J].

Chu, Chun-Yu ;

Tsai, Jin-Ting ;

Sun, Chia-Liang .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (18) :13880-13886

[4] Electrical properties of vanadium oxide thin films for bolometer applications: processed by pulse dc sputtering [J].

Fieldhouse, Nicholas ;

Pursel, Sean M. ;

Horn, Mark W. ;

Bharadwaja, S. S. N. .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2009, 42 (05)

[5] Effect of mesoporosity of vanadium oxide prepared by sol-gel process as cathodic material evaluated by cyclability during Li+ insertion/deinsertion [J].

Guerra, Elidia M. ;

Cestarolli, Dane T. ;

Oliveira, Herenilton P. .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2010, 54 (01) :93-99

[6] Electrochromic properties of porous NiO thin film as a counter electrode for NiO/WO3 complementary electrochromic window [J].

Huang, H. ;

Tian, J. ;

Zhang, W. K. ;

Gan, Y. P. ;

Tao, X. Y. ;

Xia, X. H. ;

Tu, J. P. .

ELECTROCHIMICA ACTA, 2011, 56 (11) :4281-4286

[7] Electrical and electrochemical characterization of poly (ethylene oxide)/V2O5 xerogel electrochromic films [J].

Jin, Aiping ;

Chen, Wen ;

Zhu, Quanyao ;

Yang, Ying ;

Volkov, Victor L. ;

Zakharova, Galina S. .

SOLID STATE IONICS, 2008, 179 (21-26) :1256-1262

[8] Multi-electrochromism behavior and electrochromic mechanism of electrodeposited molybdenum doped vanadium pentoxide films [J].

Jin, Aiping ;

Chen, Wen ;

Zhu, Quanyao ;

Jian, Zelang .

ELECTROCHIMICA ACTA, 2010, 55 (22) :6408-6414

[9] Structural and electrochromic properties of molybdenum doped vanadium pentoxide thin films by sol-gel and hydrothermal synthesis [J].

Jin, Aiping ;

Chen, Wen ;

Zhu, Quanyao ;

Yang, Ying ;

Volkov, V. L. ;

Zakharova, G. S. .

THIN SOLID FILMS, 2009, 517 (06) :2023-2028

[10] Preparation of aligned MnV2O6 nanorods and their anodic performance for lithium secondary battery use [J].

Lei, Shuijin ;

Tang, Kaibin ;

Jin, Yi ;

Chen, Chunhua .

NANOTECHNOLOGY, 2007, 18 (17)

← 1 2 3 4 →