Beckmann rearrangement of oximes under very mild conditions

被引：195
作者：
De Luca, L [1 ]
Giacomelli, G [1 ]
Porcheddu, A [1 ]
机构：
[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 17期
关键词：
D O I：
10.1021/jo025960d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of ketoximes, easily prepared from the corresponding ketones, undergo the Beckmann rearrangement upon treatment with 2,4,6-trichloro[1,3,5]triazine in N,N-dimethylformamide at room temperature in excellent yields. This procedure can be applied to aldoximes for obtaining the corresponding nitriles.
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页码：6272 / 6274
页数：3
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