Biopolymer based nanocomposite ionogels: high performance, sustainable and solid electrolytes

被引:42
作者
Buchtova, Nela [1 ]
Guyomard-Lack, Aurelie [1 ]
Le Bideau, Jean [1 ]
机构
[1] Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, F-44322 Nantes 3, France
关键词
IONIC LIQUIDS; MESOPOROUS SILICA; CONDUCTIVITY; DISSOLUTION; NANOFIBERS; CELLULOSE;
D O I
10.1039/c3gc42022a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ionogels based on a chemically cross-linked polysaccharide matrix and a hydrophobic ionic liquid offer a sustainable alternative to petrochemical-based polymer electrolytes. These newly obtained cellulose-based ionogels present the flexibility, thermal stability and high ionic conductivity of a liquid; this latter property can be further enhanced by adding silica nanofibers. As a result they can be used as high-performance and eco-friendly electrolytes in the production of all-solid, sustainable devices.
引用
收藏
页码:1149 / 1152
页数:4
相关论文
共 23 条
[1]   Second phase effects on the conductivity of non-aqueous salt solutions: "Soggy sand electrolytes" [J].
Bhattacharyya, AJ ;
Maier, J .
ADVANCED MATERIALS, 2004, 16 (9-10) :811-+
[2]   Synthesis and general properties of silated-hydroxypropyl methylcellulose in prospect of biomedical use [J].
Bourges, X ;
Weiss, P ;
Daculsi, G ;
Legeay, G .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2002, 99 (03) :215-228
[3]   Nanocomposite hydrogels for cartilage tissue engineering: mesoporous silica nanofibers interlinked with siloxane derived polysaccharide [J].
Buchtova, Nela ;
Rethore, Gildas ;
Boyer, Cecile ;
Guicheux, Jerome ;
Rambaud, Frederic ;
Valle, Karine ;
Belleville, Philippe ;
Sanchez, Clement ;
Chauvet, Olivier ;
Weiss, Pierre ;
Le Bideau, Jean .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2013, 24 (08) :1875-1884
[4]  
DACULSI G, 1997, Patent No. 9705911
[5]   Structural investigations of phosphate glasses: A detailed infrared study of the x(PbO)-(1-x)P2O5 vitreous system [J].
Dayanand, C ;
Bhikshamaiah, G ;
Tyagaraju, VJ ;
Salagram, M ;
Murthy, ASRK .
JOURNAL OF MATERIALS SCIENCE, 1996, 31 (08) :1945-1967
[6]   Interaction of Ionic Liquids with Polysaccharides, 8-Synthesis of Cellulose Sulfates Suitable for Polyelectrolyte Complex Formation [J].
Gericke, Martin ;
Liebert, Tim ;
Heinze, Thomas .
MACROMOLECULAR BIOSCIENCE, 2009, 9 (04) :343-353
[7]  
Guyomard-Lack A., J MAT CHEM A UNPUB
[8]   Synthesis of room temperature ionic liquids from carboxymethylated chitosan [J].
Huang, Ling ;
Zhai, Maolin ;
Peng, Jing ;
Xu, Ling ;
Li, Jiuqiang ;
Wei, Genshuan .
CARBOHYDRATE POLYMERS, 2008, 71 (04) :690-693
[9]   A facile preparation of gel materials from a solution of cellulose in ionic liquid [J].
Kadokawa, Jun-ichi ;
Murakami, Masa-aki ;
Kaneko, Yoshiro .
CARBOHYDRATE RESEARCH, 2008, 343 (04) :769-772
[10]   Ion transport and ion-filler-polymer interaction in poly(methyl methacrylate)-based, sodium ion conducting, gel polymer electrolytes dispersed with silica nanoparticles [J].
Kumar, Deepak ;
Hashmi, S. A. .
JOURNAL OF POWER SOURCES, 2010, 195 (15) :5101-5108