Studying the Three-Phase Hydrogenation of Nitrobenzene to Aniline in the Presence of a Ruthenium Catalyst

被引：2

作者：

Doluda, V. Yu ^{[1
]}

Filatova, A. E. ^{[1
]}

Sulman, E. M. ^{[1
]}

Matveeva, V. G. ^{[1
,2
]}

Mikhailov, S. P. ^{[2
]}

Sidorov, A., I ^{[1
]}

Kosivtsov, Yu Yu ^{[1
]}

机构：

[1] Tver State Tech Univ, Tver 170026, Russia

[2] Tver State Univ, Tver 170100, Russia

来源：

CATALYSIS IN INDUSTRY | 2019年 / 11卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

nitrobenzene; three-phase hydrogenation; aniline; ruthenium; hypercrosslinked polystyrene; SUPERCRITICAL CARBON-DIOXIDE; SELECTIVE HYDROGENATION; REDUCTION; MILD; NANOPARTICLES; RU;

D O I：

10.1134/S2070050419020041

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The results are presented from studying the catalytic properties of ruthenium catalyst 3% Ru/MN270 based on hypercrosslinked polystyrene in the reaction of three-phase hydrogenation of nitrobenzene to aniline. The following parameters are varied in the study: the NB concentration in the range from 0.12 to 0.24 mol/L, the catalyst concentration in the range from 1.11 x 10(-4) to 11.12 x 10(-4) mol/L, the temperature in the range from 160 to 190 degrees C, and the partial hydrogen pressure in the range from 1.013 to 0.113 MPa. The optimum parameters of the process are determined, allowing 97% conversion of nitrobenzene and a selectivity of 98% towards aniline to be achieved.

引用

页码：147 / 153

页数：7

共 36 条

[11] Polymer-supported N-heterocyclic carbene-palladium complex for heterogeneous Suzuki cross-coupling reaction [J].