Catalytic Hydrodefluorination with Late Transition Metal Complexes

被引：145

作者：

Whittlesey, Michael K. ^{[1
]}

Peris, Eduardo ^{[2
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain

来源：

ACS CATALYSIS | 2014年 / 4卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

hydrodefluorination; catalysis; transition metal complexes; fluorinated compounds; C F activation; C-F BOND; CARBON-FLUORINE BONDS; FLUOROFORM-DERIVED CUCF3; ROOM-TEMPERATURE; NUCLEOPHILIC-ATTACK; DIRECT CUPRATION; FACILE ACCESS; P-C; ACTIVATION; FLUOROARENES;

D O I：

10.1021/cs500887p

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This perspective article focuses its attention on the most recent advances in hydrodefluorination processes catalyzed by late transition metal complexes, a field that has been a matter of increasing interest during the past decade. The evolution of catalytic hydrodefluorination is treated by giving precise information on the nature of the catalysts, reductants and fluoroorganic substrates that have been used until now. An overview of the mechanistic studies that have been performed so far is also given.

引用

页码：3152 / 3159

页数：8

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