A Visible-Light-Mediated Synthesis of Carbazoles

被引：175

作者：

Hernandez-Perez, Augusto C. ^{[1
,2
]}

Collins, Shawn K. ^{[1
,2
]}

机构：

[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada

[2] Univ Montreal, Ctr Green Chem & Catalysis, Montreal, PQ H3C 3J7, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 48期

基金：

加拿大自然科学与工程研究理事会;

关键词：

carbazoles; copper; heterocycles; photochemistry; PALLADIUM-CATALYZED SYNTHESIS; PHOTOREDOX CATALYSIS; PHOTOPHYSICAL PROPERTIES; PHOTOCHEMISTRY; DERIVATIVES; COMPLEXES; DEVICES; GREEN; PHOTOCYCLIZATION; DIPHENYLAMINES;

D O I：

10.1002/anie.201306920

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photosynthetic preparation of N-aryl- and N-alkyl-bearing carbazoles utilizes continuous flow, visible light, and an in situ formed Cu-based sensitizer (see picture). The method is mild and efficient, and allows the straightforward synthesis of a variety of carbazoles with different substituents, heterocycles, and complex carbon architectures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12696 / 12700

页数：5

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