A Visible-Light-Mediated Synthesis of Carbazoles

被引：175
作者：
Hernandez-Perez, Augusto C. [1 ,2 ]
Collins, Shawn K. [1 ,2 ]
机构：
[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada
[2] Univ Montreal, Ctr Green Chem & Catalysis, Montreal, PQ H3C 3J7, Canada
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 48期
基金：
加拿大自然科学与工程研究理事会;
关键词：
carbazoles; copper; heterocycles; photochemistry; PALLADIUM-CATALYZED SYNTHESIS; PHOTOREDOX CATALYSIS; PHOTOPHYSICAL PROPERTIES; PHOTOCHEMISTRY; DERIVATIVES; COMPLEXES; DEVICES; GREEN; PHOTOCYCLIZATION; DIPHENYLAMINES;
D O I：
10.1002/anie.201306920
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photosynthetic preparation of N-aryl- and N-alkyl-bearing carbazoles utilizes continuous flow, visible light, and an in situ formed Cu-based sensitizer (see picture). The method is mild and efficient, and allows the straightforward synthesis of a variety of carbazoles with different substituents, heterocycles, and complex carbon architectures. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12696 / 12700
页数：5
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