Synergistic reinforcing of poly(lactic acid) by poly(butylene adipate-co-terephthalate) and alumina nanoparticles

被引:23
作者
Chen, Jie [1 ]
Hu, Rong-Rong [2 ]
Jin, Fan-Long [1 ]
Park, Soo-Jin [3 ]
机构
[1] Jilin Inst Chem Technol, Dept Polymer Mat, Jilin 132022, Jilin, Peoples R China
[2] Zhu Hai CosMX Battery Co Ltd, Zhu Hai City, Peoples R China
[3] Inha Univ, Dept Chem, Incheon 22212, South Korea
关键词
biodegradable; biomaterials; biopolymers and renewable polymers; THERMOMECHANICAL PROPERTIES; MECHANICAL-PROPERTIES; IMPACT STRENGTH; MORPHOLOGY; BEHAVIOR; BLENDS; PBAT; PLA; TEMPERATURE; IMPROVEMENT;
D O I
10.1002/app.50250
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Biodegradable poly(lactic acid) (PLA)/poly(butylene adipate-co-terephthalate) (PBAT) blends and PLA/PBAT/Al2O3 nanocomposites were fabricated via solution blending. The influence of PBAT and Al2O3 content on the thermal stability, flexural properties, impact strength, and morphology of both the PLA/PBAT blends and the PLA/PBAT/Al2O3 nanocomposites were investigated. The impact strength of the PLA/PBAT/Al2O3 nanocomposites containing 5 wt% PBAT increased from 4.3 to 5.2 kJ/m(2) when the Al2O3 content increased from 0 to 1 wt%. This represents a 62% increase compared to the impact strength of pristine PLA and a 20% increase compared to the impact strength of PLA/PBAT blends containing 5 wt% PBAT. Scanning electron microscopy imaging revealed that the Al2O3 nanoparticles in the PLA/PBAT/Al2O3 nanocomposites function as a compatibilizer to improve the interfacial interaction between the PBAT and the PLA matrix.
引用
收藏
页数:9
相关论文
共 46 条
[1]   Synergized poly(lactic acid)-hydroxyapatite composites: Biocompatibility study [J].
Akindoyo, John O. ;
Beg, Mohammad D. H. ;
Ghazali, Suriati ;
Alam, A. K. M. M. ;
Heim, Hans P. ;
Feldmann, Maik .
JOURNAL OF APPLIED POLYMER SCIENCE, 2019, 136 (15)
[2]  
Araujo J. P., 2019, MATER CHEM PHYS, V237
[3]   A comprehensive study on shape memory behavior of PEG plasticized PLA/TPU bio-blends [J].
Boyacioglu, S. ;
Kodal, M. ;
Ozkoc, G. .
EUROPEAN POLYMER JOURNAL, 2020, 122
[4]   Structuring poly (lactic acid) film with excellent tensile toughness through extrusion blow molding [J].
Cao Zengwen ;
Lu, Zhifeng ;
Pan, Hongwei ;
Bian, Junjia ;
Han, Lijing ;
Zhang, Huiliang ;
Dong, Lisong ;
Yang, Yuming .
POLYMER, 2020, 187
[5]   The effect of the interfacial assembly of nano-silica in poly(lactic acid)/poly(butylene adipate-co-terephthalate) blends on morphology, rheology and mechanical properties [J].
Dil, Ebrahim Jalali ;
Virgilio, Nick ;
Favis, Basil D. .
EUROPEAN POLYMER JOURNAL, 2016, 85 :635-646
[6]   PLA-PBAT-PLA tri-block copolymers: Effective compatibilizers for promotion of the mechanical and rheological properties of PLA/PBAT blends [J].
Ding, Yue ;
Lu, Bo ;
Wang, Pingli ;
Wang, Gexia ;
Ji, Junhui .
POLYMER DEGRADATION AND STABILITY, 2018, 147 :41-48
[7]   Carbonized cellulose nanofibers as dielectric heat sources for microwave annealing 3D printed PLA composite [J].
Dong, Ju ;
Huang, Xingyan ;
Muley, Pranjali ;
Wu, Tongyao ;
Barekati-Goudarzi, Mohamad ;
Tang, Zhengjie ;
Li, Meichun ;
Lee, Sunyoung ;
Boldor, Dorin ;
Wu, Qinglin .
COMPOSITES PART B-ENGINEERING, 2020, 184
[8]   Rubber Toughening of Polylactic Acid (PLA) with Poly(butylene adipate-co-terephthalate) (PBAT): Mechanical Properties, Fracture Mechanics and Analysis of Ductile-to-Brittle Behavior while Varying Temperature and Test Speed [J].
Gigante, Vito ;
Canesi, Ilaria ;
Cinelli, Patrizia ;
Coltelli, Maria Beatrice ;
Lazzeri, Andrea .
EUROPEAN POLYMER JOURNAL, 2019, 115 :125-137
[9]   Interfacial toughness properties of trifunctional epoxy resins/calcium carbonate nanocomposites [J].
Jin, Fan-Long ;
Park, Soo-Jin .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 475 (1-2) :190-193
[10]   Improved impact strength of poly(lactic acid) by incorporating poly(butylene succinate) and silicon dioxide nanoparticles [J].
Jin, Fan-Long ;
Hu, Rong-Rong ;
Park, Soo-Jin .
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2020, 37 (05) :905-910