An exact coordination mode of 6-thiopurine with an organotin(IV): preparation and crystal structure of triphenyl(6-thiopurinyl)tin(IV)

被引：2
|
作者：
Zhang, RF
Li, F
Ma, CL
机构：
[1] Liaoning Univ, Dept Chem, Liaocheng 252059, Peoples R China
[2] Taishan Univ, Tai An 271021, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 09期
基金：
中国国家自然科学基金;
关键词：
crystal structure; coordination mode; donor atom; 6-thiopurine;
D O I：
10.1016/j.ica.2004.03.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Triphenyl(6-thiopurinyl)tin has been prepared and its structure reinvestigated by X-ray diffraction. In the structure, a new coordination mode was observed that was different from those reported previously from investigations by infrared and Mossbauer spectroscopy. In the molecule, 6-thiopurine coordinated to tin by the S and N(1) atoms. The discrete molecules were connected to form a zigzag ID network through intermolecular (HN)-N-... hydrogen bonds. The tin environment is pentacoordinated with cis-trigonal bipyramidal geometry. (C) 2004 Published by Elsevier B.V.
引用
收藏
页码：2759 / 2762
页数：4
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