The Investigation of Free Radical Intermolecular Addition Following Free Radical SH2' Cyclization Reactions

被引：0

作者：

Wu, Yuh-Wern ^{[1
]}

Wang, Pai-Lin ^{[1
]}

Kong, Yao-Zhang ^{[1
]}

Chen, Ai-Ru ^{[1
]}

Yang, Jyh-Ferng ^{[1
]}

机构：

[1] I Shou Univ, Dept Chem Engn, Kaohsiung 84008, Taiwan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2014年 / 61卷 / 05期

关键词：

Free radical S(H)2 reaction; Radical intermolecular addition; Cyclization reaction; MEDIUM-SIZED RINGS; 5-EXO-TRIG CYCLIZATIONS; HALIDES; 3-SILYLHEPTA-1,6-DIENES; MECHANISM; ACID;

D O I：

10.1002/jccs.201300185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photolytic radical intermolecular addition following S(H)2 cyclization reactions of t-BuHgCl with 1-bromo-4-(2-choroallyloxy)-but-2-ene and (E)-4-bromobut-2-enyl acrylate gave the good yields and the chemoselectivity of the cyclized product. The high stereoselectivity of the reactions is discussed.

引用

页码：605 / 608

页数：4

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