Ruthenium-catalyzed alkenylation of azoxybenzenes with alkenes through ortho-selective C-H activation

被引：65
作者：
Li, Hongji [1 ]
Xie, Xiaoyu [1 ]
Wang, Lei [1 ,2 ]
机构：
[1] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 32期
基金：
美国国家科学基金会;
关键词：
ALPHA-OXOCARBOXYLIC ACIDS; DIRECTING GROUP; ORTHO-ACYLATION; BOND FUNCTIONALIZATIONS; ORGANIC-SYNTHESIS; COMPOSITE FILMS; LIQUID-CRYSTAL; DIRECT ACCESS; OLEFINATION; PALLADIUM;
D O I：
10.1039/c4cc00449c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly selective alkenylation of azoxybenzenes catalyzed by the Ru-III-complex was developed. It provides a direct access to a series of olefinated azoxy compounds in good yields.
引用
收藏
页码：4218 / 4221
页数：4
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