Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins

被引：72

作者：

Liu, Yiyang ^{[1
]}

Kim, Kelly E. ^{[1
]}

Herbert, Myles B. ^{[1
]}

Fedorov, Alexey ^{[1
]}

Grubbs, Robert H. ^{[1
]}

Stoltz, Brian M. ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Warren & Katharine Schlinger Lab Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 01期

关键词：

decarbonylative dehydration; fatty acids; large-scale process; linear alpha olefins; palladium; renewable feedstocks; Z-selective metathesis; ALIPHATIC CARBOXYLIC-ACIDS; ALKENES; CONVERSION; ETHYLENE;

D O I：

10.1002/adsc.201301109

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A highly efficient palladium-catalyzed decarbonylative dehydration reaction of carboxylic acids is reported. This method transforms abundant and renewable even-numbered natural fatty acids into valuable and expensive odd-numbered alpha olefins. Additionally, the chemistry displays a high functional group tolerance. The process employs a low loading of palladium catalyst and proceeds under solvent-free and relatively mild conditions.

引用

页码：130 / 136

页数：7

共 23 条

[1]

ALJARALLAH AM, 1992, CATAL TODAY, V14, pR9

[2] SILVER(II) COMPLEXES IN OXIDATIVE DECARBOXYLATION OF ACIDS [J].