Facile Synthesis of BiVO4 for Visible-Light-Induced C-C Bond Cleavage of Alkenes to Generate Carbonyls

被引：34

作者：

Han, Sung Su ^{[1
]}

Park, Joon Yong ^{[2
,3
]}

Hwang, Ho Seong ^{[1
]}

Choe, Hye Rin ^{[2
,3
]}

Nam, Ki Min ^{[2
,3
]}

Cho, Eun Jin ^{[1
]}

机构：

[1] Chung Ang Univ, Dept Chem, 84 Heukseok Ro, Seoul 06974, South Korea

[2] Pusan Natl Univ, Dept Chem, Busan 46241, South Korea

[3] Pusan Natl Univ, Chem Inst Funct Mat, Busan 46241, South Korea

来源：

CHEMSUSCHEM | 2019年 / 12卷 / 13期

基金：

新加坡国家研究基金会;

关键词：

alkene; bismuth vanadate; C-C bond cleavage; molecular oxygen; photocatalysis; PHOTOCATALYTIC AEROBIC OXIDATION; SELECTIVE OXIDATION; GREEN CHEMISTRY; EFFICIENT; OLEFINS; AMINES; ALCOHOLS; COMPLEX; IMINES; DRIVEN;

D O I：

10.1002/cssc.201900439

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

BiVO4 crystals synthesized by an ultrasonic-assisted method (Sono-BiVO4) showed improved efficiency as a heterogeneous photocatalyst under visible-light irradiation. Sono-BiVO4 was successfully used for the C-C bond cleavage of alkenes to generate carbonyl compounds. Styrene derivatives were converted into carbonyl compounds in the presence of Sono-BiVO4 under highly sustainable conditions requiring only natural sources, that is, molecular oxygen, visible light, and water at room temperature. Additionally, Sono-BiVO4 could be easily separated from the reaction mixture and reused.

引用

页码：3018 / 3022

页数：5

共 38 条

[1]

Anastas P.T., 1998, GREEN CHEM THEORY PR

[2]

[Anonymous], 2013, ANGEW CHEM, V125, P7516

[3] Applications of Continuous-Flow Photochemistry in Organic Synthesis, Material Science, and Water Treatment [J].

Cambie, Dario ;

Bottecchia, Cecilia ;

Straathof, Natan J. W. ;

Hessel, Volker ;

Noel, Timothy .

CHEMICAL REVIEWS, 2016, 116 (17) :10276-10341

[4] Controlled Fluoroalkylation Reactions by Visible-Light Photoredox Catalysis [J].

Chatterjee, Tanmay ;

Iqbal, Naeem ;

You, Youngmin ;

Cho, Eun Jin .

ACCOUNTS OF CHEMICAL RESEARCH, 2016, 49 (10) :2284-2294

[5] A Highly Efficient Catalyst for Selective Oxidative Scission of Olefins to Aldehydes: Abnormal-NHC-Ru(II) Complex in Oxidation Chemistry [J].

Daw, Prosenjit ;

Petakamsetty, Ramu ;

Sarbajna, Abir ;

Laha, Siladitya ;

Ramapanicker, Ramesh ;

Bera, Jitendra K. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (40) :13987-13990

[6] Recent developments in heterogeneous photocatalytic water treatment using visible light-responsive photocatalysts: a review [J].

Dong, Shuying ;

Feng, Jinglan ;

Fan, Maohong ;

Pi, Yunqing ;

Hu, Limin ;

Han, Xiao ;

Liu, Menglin ;

Sun, Jingyu ;

Sun, Jianhui .

RSC ADVANCES, 2015, 5 (19) :14610-14630

[7] Photocatalytic Oxidation of Alcohols over TiO2 Covered with Nb2O5 [J].

Furukawa, Shinya ;

Shishido, Tetsuya ;

Teramura, Kentaro ;

Tanaka, Tsunehiro .

ACS CATALYSIS, 2012, 2 (01) :175-179

[8] Using Singlet Oxygen to Synthesize Natural Products and Drugs [J].

Ghogare, Ashwini A. ;

Greer, Alexander .

CHEMICAL REVIEWS, 2016, 116 (17) :9994-10034

[9] Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2 [J].

Gonzalez-de-Castro, Angela ;

Xiao, Jianliang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (25) :8206-8218

[10] Photocatalytic Reduction of CO2 on TiO2 and Other Semiconductors [J].

Habisreutinger, Severin N. ;

Schmidt-Mende, Lukas ;

Stolarczyk, Jacek K. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (29) :7372-7408

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