Ruthenium-Catalyzed Hydroformylation of Alkenes by using Carbon Dioxide as the Carbon Monoxide Source in the Presence of Ionic Liquids

被引：73

作者：

Ali, Meher ^{[1
]}

Gual, Aitor ^{[1
]}

Ebeling, Guenter ^{[1
]}

Dupont, Jairton ^{[1
]}

机构：

[1] Univ Fed Rio Grande do Sul, Inst Chem, Lab Mol Catalysis, BR-91501970 Porto Alegre, RS, Brazil

来源：

CHEMCATCHEM | 2014年 / 6卷 / 08期

关键词：

carbon dioxide; hydroformylation; ionic liquids; reverse water gas shift; ruthenium; HETEROCYCLIC CARBENE COMPLEXES; ONE-POT HYDROFORMYLATION; RH/RU DUAL CATALYST; TANDEM HYDROFORMYLATION/HYDROGENATION; METAL; HYDROGENATION; EFFICIENT; HYDROAMINOMETHYLATION; ACTIVATION; RHODIUM;

D O I：

10.1002/cctc.201402226

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of [BMI center dot Cl] (BMI = 1-butyl-3-methylimidazolium) or [BMMI center dot Cl] (BMMI = 3-butyl-1,2-dimethylimidazolium) with Ru-3(CO)(12) generates Ru-hydride-carbonyl-carbene species in situ that are efficient catalysts for a reverse water gas shift/hydroformylation/hydrogenation cascade reaction. The addition of H3PO4 increased the catalytic activity of the first step (i.e., the hydrogenation of CO2 to CO). Under the optimized reaction conditions [120 degrees C and 6.0 MPa CO2/H-2 (1:1) for 17 h], cyclohexene and 2,2-disubstituted alkenes were easily functionalized to alcohols through sequential hydroformylation/carbonyl reduction.

引用

页码：2224 / 2228

页数：5

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