Synthesis, Properties of a Photochromic Diarylethene Material Bearing Benzofuran and Thiazole Rings

被引:0
作者
Geng, Weiwei [1 ]
Fan, Congbin [1 ]
Li, Hui [1 ]
Cui, Shiqiang [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源
ADVANCED RESEARCH ON MATERIAL ENGINEERING, CHEMISTRY AND ENVIRONMENT | 2013年 / 788卷
关键词
diarylethene; photochromism; fluorescence; FLUORESCENCE; DITHIENYLETHENES; UNIT;
D O I
10.4028/www.scientific.net/AMR.788.186
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new photochromic diarylethene compound, 1-(2-methylbenzofuran)-2-[(2,4-dimethyl-5-thiazolyl]perfluorocyclopentene (1o), was synthesized, and its photochromic reactivity, fluorescent were also investigated. The results showed that this compound exhibited reversible photochromism, changing from colorless to yellow after irradiation with UV light both in solution and in PMMA amorphous film In hexane solution, the openring isomer of the diarylethene 1 exhibited relatively strong fluorescence at 410 mu when excited at 307 am.
引用
收藏
页码:186 / 189
页数:4
相关论文
共 10 条
[1]   Study on photochromism of diarylethenes with a 2,5-dihydropyrrole bridging unit: A convenient preparation of 3,4-diarylpyrroles from 3,4-diaryl-2,5-dihydropyrroles [J].
Chen, Y ;
Zeng, DX ;
Xie, N ;
Dang, YZ .
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (13) :5001-5005
[2]   Substituent position effect on the properties of isomeric photochromic diarylethenes bearing chlorine atoms [J].
Fan, Congbin ;
Pu, Shouzhi ;
Liu, Gang ;
Yang, Tianshe .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 194 (2-3) :333-343
[3]   Fluorescence of photochromic 1,2-bis(3-methyl-2-thienyl)ethene [J].
Fukaminato, T ;
Kawai, T ;
Kobatake, S ;
Irie, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (33) :8372-8377
[4]  
Irie M., 2001, PHOTOSWITCHABLE MOL
[5]   Photochromic reaction and fluorescence of dithienylethenes in the solid state [J].
Kasatani, K ;
Kambe, S ;
Irie, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1999, 122 (01) :11-15
[6]   Diarylethene as a photo switching unit [J].
Matsuda, K ;
Irie, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2004, 5 (02) :169-182
[7]   Photoregulation of fluorescence in a porphyrinic dithienylethene photochrome [J].
Norsten, TB ;
Branda, NR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (08) :1784-1785
[8]   Photochromic diarylethenes for three-wavelength optical memory [J].
Pu, SZ ;
Zhang, FS ;
Xu, JK ;
Shen, L ;
Xiao, Q ;
Chen, B .
MATERIALS LETTERS, 2006, 60 (04) :485-489
[9]   Syntheses and optoelectronic properties of four photochromic dithienylethenes [J].
Pu, SZ ;
Yang, TS ;
Xu, JK ;
Shen, L ;
Li, GZ ;
Xiao, Q ;
Chen, B .
TETRAHEDRON, 2005, 61 (27) :6623-6629
[10]   Recent progresses on diarylethene based photochromic switches [J].
Tian, H ;
Yang, SJ .
CHEMICAL SOCIETY REVIEWS, 2004, 33 (02) :85-97