Efficient Synthesis and Properties of a Photochromic Hybrid Diarylethene Bearing a Pyrimidine Moiety

被引:1
作者
Yu, Xiaodong [1 ]
Liu, Hongliang [1 ]
Liu, Gang [1 ]
Pu, Shouzhi [1 ]
机构
[1] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源
ADVANCED RESEARCH ON MATERIAL SCIENCE, ENVIROMENT SCIENCE AND COMPUTER SCIENCE III | 2014年 / 886卷
关键词
Diarylethene; Pyrimidine; Photochromism; Kinetics; Fluorescence; FLUORESCENCE; MEMORIES; DESIGN;
D O I
10.4028/www.scientific.net/AMR.886.159
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel photochromic diarylethene bearing a six-membered pyrimidine as one aryl moiety was synthesized to investigate its photochromic behaviors. The diarylethene exhibited good photochromism and functioned as a fluorescence switch both in hexane and in PMMA film. The fluorescence had a remarkable initial increase with subsequent dramatic decrease with increasing concentration. The results suggested that the pyrimidine moiety played a vital role during the process of photoisomerization reaction for the diarylethene.
引用
收藏
页码:159 / 163
页数:5
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