Pregnane glycosides from Hemidesmus indicus

被引:30
作者
Deepak, D
Srivastava, S
Khare, A
机构
[1] Department of Chemistry, University of Lucknow
关键词
Hemidesmus indicus; Asclepiadaceae; pregnane glycosides; medidesmine; hemisine; desmisine;
D O I
10.1016/S0031-9422(96)00393-7
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Three new pregnane oligoglycosides, medidesmine, hemisine and desmisine isolated from the plant Hemidesmus indicus were identified as sarcostin-3-O-alpha-D-glucopyranosyl (1 --> 4)-O-beta-D-digitoxopyranosyl (1 --> 4)-O-beta-D-oleandropyranoside, calogenin-3-O-beta-D-cymaropyranosyl (I --> 4)-O[3-O-methyl]beta-D-glucopyranosyl (1 --> 4)-O-beta-D-glucopyranosyl (1 --> 4)-O-beta-D-cymaropyranoside and calogenin-3-O-beta-D-xylopyranosyl (1 --> 4)-O-beta-D-digitoxopyranosyl (1 --> 4)-O-beta-D-xylopyranosyl (1 --> 4)-O-beta-D-digitoxopyranoside, respectively, with the help of FAB-MS, EI-MS, H-1 and C-13 NMR spectroscopy. along with chemical transformations. Copyright (C) 1996 Published by Elsevier Science Ltd
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页码:145 / 151
页数:7
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