High-energy cobalt hexacyanoferrate and carbon micro-spheres aqueous sodium-ion capacitors

被引:93
作者
Lu, Ke [1 ]
Song, Bin [2 ]
Gao, Xiang [1 ]
Dai, Hongxiu [1 ]
Zhang, Jintao [1 ]
Ma, Houyi [1 ]
机构
[1] Shandong Univ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, State Educ Minist, Jinan 250100, Peoples R China
[2] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China
基金
中国国家自然科学基金;
关键词
Sodium-ion intercalation; Energy storage; Sodium-ion pseudocapacitor; Cobalt hexacyanoferrate; OPEN FRAMEWORK; BATTERY ELECTRODES; CATHODE MATERIAL; COPPER; NANOSTRUCTURES; CAPABILITY; COMPOSITE;
D O I
10.1016/j.jpowsour.2015.11.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sodium-based intercalation aqueous pseudocapacitive energy systems are attractive because of their obvious advantages including improved safety, low cost and environmental friendliness. Herein, an aqueous sodium-ion capacitor with the cobalt hexacyanoferrate (CoHCF) as the cathode electrode and carbon micro-spheres (CMS) as the anode electrode was fabricated, showing an extended operating voltage window (2 V), excellent capacitance behaviour, and high energy density (54.4 Wh kg(-1)). The present results provide meaningful clues to design new intercalation pseudocapacitor for future practical applications. And these remarkable features may pave the way to next-generation large-scale production of high performance hybrid supercapacitors performed as regulation or complementary devices. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:347 / 353
页数:7
相关论文
共 40 条
[1]   Green energy storage chemistries based on neutral aqueous electrolytes [J].
Chang, Zheng ;
Yang, Yaqiong ;
Li, Minxia ;
Wang, Xiaowei ;
Wu, Yuping .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (28) :10739-10755
[2]   Electrochemical supercapacitor behavior of Ni3(Fe(CN)6)2(H2O) nanoparticles [J].
Chen, Jie ;
Huang, Kelong ;
Liu, Suqin ;
Hu, Xi .
JOURNAL OF POWER SOURCES, 2009, 186 (02) :565-569
[3]   High-Performance Sodium-Ion Pseudocapacitors Based on Hierarchically Porous Nanowire Composites [J].
Chen, Zheng ;
Augustyn, Veronica ;
Jia, Xilai ;
Xiao, Qiangfeng ;
Dunn, Bruce ;
Lu, Yunfeng .
ACS NANO, 2012, 6 (05) :4319-4327
[4]   Electrochemical preparation, characterization and application of electrodes modified with hybrid hexacyanoferrates of copper and cobalt [J].
Cui, XP ;
Hong, L ;
Lin, XQ .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2002, 526 (1-2) :115-124
[5]   Asymmetric Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density [J].
Fan, Zhuangjun ;
Yan, Jun ;
Wei, Tong ;
Zhi, Linjie ;
Ning, Guoqing ;
Li, Tianyou ;
Wei, Fei .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (12) :2366-2375
[6]  
Gao S., 2014, ANGEW CHEM INT EDIT, V53, P1
[7]   Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance [J].
Ghidiu, Michael ;
Lukatskaya, Maria R. ;
Zhao, Meng-Qiang ;
Gogotsi, Yury ;
Barsoum, Michel W. .
NATURE, 2014, 516 (7529) :78-U171
[8]   A self-assembled hierarchical nanostructure comprising carbon spheres and graphene nanosheets for enhanced supercapacitor performance [J].
Guo, Chun Xian ;
Li, Chang Ming .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (11) :4504-4507
[9]   Design and Synthesis of Hierarchical MnO2 Nanospheres/Carbon Nanotubes/Conducting Polymer Ternary Composite for High Performance Electrochemical Electrodes [J].
Hou, Ye ;
Cheng, Yingwen ;
Hobson, Tyler ;
Liu, Jie .
NANO LETTERS, 2010, 10 (07) :2727-2733
[10]   Al-doped α-MnO2 for high mass-loading pseudocapacitor with excellent cycling stability [J].
Hu, Zhimi ;
Xiao, Xu ;
Chen, Chi ;
Li, Tianqi ;
Huang, Liang ;
Zhang, Chuanfang ;
Su, Jun ;
Miao, Ling ;
Jiang, Jianjun ;
Zhang, Yanrong ;
Zhou, Jun .
NANO ENERGY, 2015, 11 :226-234