Photocatalytic efficiency of graphene/nickel oxide nanocomposites towards the degradation of anionic and cationic dye molecules under visible light

被引:15
作者
Maruthupandy, Muthuchamy [1 ,2 ]
Muneeswaran, Thillaichidambaram [2 ]
Vennila, Thirumalaiswamy [3 ]
Vaishali, C. V. [4 ]
Anand, Muthusamy [5 ]
Cho, Wan-Seob [1 ]
Quero, Franck [2 ,6 ]
机构
[1] Dong A Univ, Grad Sch, Dept Hlth Sci, Lab Toxicol, 37 Nakdong Daero,550 Beon Gil, Busan 49315, South Korea
[2] Univ Chile, Fac Ciencias Fis & Matemat, Dept Ingn Quim Biotecnol & Mat, Avenida Beauchef 851, Santiago 8370456, Chile
[3] Sri Sairam Engn Coll, Dept Chem, Chennai 600044, Tamil Nadu, India
[4] JSS Acad Higher Educ & Res, Sch Life Sci, Mysore 570015, Karnataka, India
[5] Madurai Kamaraj Univ, Dept Marine & Coastal Studies, Madurai 625021, Tamil Nadu, India
[6] Millennium Nucl Smart Soft Mech Metamat, Avenida Beauchef 851, Santiago 8370456, Chile
关键词
Nickel oxide; Graphene; Nanocomposites; Methylene blue and methyl orange; Photocatalytic degradation; Visible light; NIO NANOPARTICLES; COMPOSITE; ADSORPTION;
D O I
10.1016/j.jphotochem.2022.113819
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Simplified synthesis of nickel oxide nanorods (NiO NRs) and graphene/NiO nanocomposites (Grn/NiO NCs) was achieved using a chemical reduction approach of Grn and nickel chloride precursors. The crystalline nature of the prepared NiO NRs and Grn/NiO NCs was investigated using X-ray diffraction analysis, and the surface morphology was examined using transmission electron microscope. We examined the phtocatalytic efficiency of Grn/NiO NCs against anionic and cationic dye molecules. The Grn/NiO NCs showed 100% photocatalytic activity for methylene blue (MB) and methyl orange (MO) dye molecules within 90 and 120 min, respectively. The presence of Grn sheets has enhance the photocatalytic activity of NCs under visible light irradiation by reducing the recombination of excited electrons in the conduction band (CB) with holes in the valence band (VB) when Grn/NiO NCs reacted with dyes. We have developed efficient visible light functionalized Grn/NiO NCs photo-catalysts for practical environmental applications using simple and cost-effective approach for large-scale manufacturing.
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页数:10
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