Recent Progress of Inverted Perovskite Solar Cells with a Modified PEDOT:PSS Hole Transport Layer

被引：122

作者：

Han, Wenbin ^{[1
]}

Ren, Guanhua ^{[1
]}

Liu, Jiuming ^{[2
]}

Li, Zhiqi ^{[1
]}

Bao, Hongchang ^{[1
]}

Liu, Chunyu ^{[1
,3
]}

Guo, Wenbin ^{[1
]}

机构：

[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China

[2] Shanghai Technol Univ, Sch Informat Sci & Technol, Shanghai 201210, Peoples R China

[3] Jilin Univ, Coll Mat Sci & Engn, Changchun 130012, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2020年 / 12卷 / 44期

关键词：

inverted perovskite solar cells; PEDOT:PSS; hole transport layer; charge transport; moisture stability;

D O I：

10.1021/acsami.0c13576

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Organic-inorganic hybrid perovskite solar cells (PSCs) has achieved the power conversion efficiency (PCE) of 25.2% in the last 10 years, and the PCE of inverted PSCs has reached >22%. The rapid enhancement has partly benefited from the employment of suitable hole transport layers. Especially, poly( 3,4-ethenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is one of the most widely used polymer hole transport materials in inverted PSCs, because of its high optical transparency in the visible region and low-temperature processing condition. However, the PCE and stability of PSCs based on pristine PEDOT:PSS are far from satisfactory, which are ascribed to low fitness between PEDOT:PSS and perovskite materials, in terms of work function, conductivity, film growth, and hydrophobicity. This paper summaries recent progress regarding to modifying/remedy the drawbacks of PEDOT:PSS to improve the PCE and stability. The systematically understanding of the mechanism of modified PEDOT:PSS and various characteristic methods are summarized here. This Review has the potential to guide the development of PSCs based on commercial PEDOT:PSS.

引用

页码：49297 / 49322

页数：26

共 140 条

[1] Interface Engineering of a Compatible PEDOT Derivative Bilayer for High-Performance Inverted Perovskite Solar Cells [J].

Bao, Xichang ;

Wang, Junyi ;

Li, Yuan ;

Zhu, Dangqiang ;

Wu, Ying ;

Guo, Peipei ;

Wang, Xuefei ;

Zhang, Yongchao ;

Wang, Jiuxing ;

Yip, Hin-Lap ;

Yang, Renqiang .

ADVANCED MATERIALS INTERFACES, 2017, 4 (06)

[2] Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells [J].

Bi, Cheng ;

Wang, Qi ;

Shao, Yuchuan ;

Yuan, Yongbo ;

Xiao, Zhengguo ;

Huang, Jinsong .

NATURE COMMUNICATIONS, 2015, 6

[3]

Bubnova O, 2014, NAT MATER, V13, P190, DOI [10.1038/NMAT3824, 10.1038/nmat3824]

[4] Black Phosphorus Quantum Dots for Hole Extraction of Typical Planar Hybrid Perovskite Solar Cells [J].

Chen, Wei ;

Li, Kaiwen ;

Wang, Yao ;

Feng, Xiyuan ;

Liao, Zhenwu ;

Su, Qicong ;

Lin, Xinnan ;

He, Zhubing .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (03) :591-598

[5] Enhanced Efficiencies of Perovskite Solar Cells by Incorporating Silver Nanowires into the Hole Transport Layer [J].

Cheng, Chien-Jui ;

Balamurugan, Rathinam ;

Liu, Bo-Tau .

MICROMACHINES, 2019, 10 (10)

[6] Organic Small Molecule as the Underlayer Toward High Performance Planar Perovskite Solar Cells [J].

Cong, Shan ;

Yang, Hao ;

Lou, Yanhui ;

Han, Liang ;

Yi, Qinghua ;

Wang, Haibo ;

Sun, Yinghui ;

Zou, Guifu .

ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (03) :2295-2300

[7] Quantification of Geminate and Non-Geminate Recombination Losses within a Solution-Processed Small-Molecule Bulk Heterojunction Solar Cell [J].

Credgington, Dan ;

Jamieson, Fiona C. ;

Walker, Bright ;

Thuc-Quyen Nguyen ;

Durrant, James R. .

ADVANCED MATERIALS, 2012, 24 (16) :2135-2141

[8] The origin of the high conductivity of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT- PSS) plastic electrodes [J].

Crispin, X. ;

Jakobsson, F. L. E. ;

Crispin, A. ;

Grim, P. C. M. ;

Andersson, P. ;

Volodin, A. ;

van Haesendonck, C. ;

Van der Auweraer, M. ;

Salaneck, W. R. ;

Berggren, M. .

CHEMISTRY OF MATERIALS, 2006, 18 (18) :4354-4360

[9] Reduced Self-Doping of Perovskites Induced by Short Annealing for Efficient Solar Modules [J].

Deng, Yehao ;

Ni, Zhenyi ;

Palmstrom, Axel F. ;

Zhao, Jingjing ;

Xu, Shuang ;

Van Brackle, Charles H. ;

Xiao, Xun ;

Zhu, Kai ;

Huang, Jinsong .

JOULE, 2020, 4 (09) :1949-1960

[10] Inverted CH3NH3PbI3 perovskite solar cells based on solution-processed V2O5 film combined with P3CT salt as hole transport layer [J].

Duan, Chenghao ;

Zhao, Min ;

Zhao, Chengjie ;

Wang, Yao ;

Li, Jiangsheng ;

Han, Wei ;

Hu, Quanqin ;

Yao, Lili ;

Jian, Hongmei ;

Lu, Fushen ;

Jiu, Tonggang .

MATERIALS TODAY ENERGY, 2018, 9 :487-495

← 1 2 3 4 5 6 7 8 9 10 →