Temperature effect on the electronic spectra of poly(p-phenylenevinylene)

被引:58
|
作者
Yu, JW
Hayashi, M
Lin, SH
Liang, KK
Hsu, JH
Fann, WS
Chao, CI
Chuang, KR
Chen, SA
机构
[1] NATL TAIWAN UNIV,DEPT PHYS,TAIPEI 10764,TAIWAN
[2] NATL TSING HUA UNIV,DEPT CHEM ENGN,HSINCHU,TAIWAN
关键词
poly(p-phenylenevinylene); electronic spectra; temperature effect;
D O I
10.1016/S0379-6779(96)03784-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The experimental temperature-dependent absorption, phogtoluminescence and photoluminescence excitation spectra of poly(p-phenylenevinylene) (PPV) are presented and a molecular theory is used to analyze the results. In order to model the complicated system such as PPV, the structural inhomogeneity has to be included. The structural inhomogeneity is represented by the different Huang-Rhys factors associated with different chain lengths. The theoretical spectra agree qualitatively with the experimental results.
引用
收藏
页码:159 / 166
页数:8
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