A Convenient One-Pot Synthesis of β-(Trifluoromethyl)allylaminophosphonic and Benzylaminophosphonic Acids

被引：3

作者：

Cal, Dariusz ^{[1
]}

Bartnik, Romuald ^{[1
]}

机构：

[1] Univ Lodz, Dept Organ & Appl Chem, PL-90136 Lodz, Poland

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 04期

关键词：

Allylaminophosphonic acids; benzylamino-phosphonic acids; reductive amination; -(trifluoromethyl)acroleins; AMINO-ACIDS; DERIVATIVES; INHIBITORS; DISCOVERY; FLUORINE; BOND;

D O I：

10.1080/10426500902737364

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reductive condensation of aminoalkylphosphonic acids with beta-chloro- or beta-ethylthio-(beta-trifluoromethyl)acroleins leads to secondary (trifluoromethyl)allylaminophosphonic acids in moderate to good yields. The method appears to be useful for the preparation of benzylaminophosphonic acids.

引用

页码：1054 / 1064

页数：11

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