Selective hydrogenation of biomass-derived ethyl levulinate to γ-valerolactone over supported Co catalysts in continuous process at atmospheric pressure

被引：32

作者：

Kondeboina, Murali ^{[1
]}

Enumula, Siva Sankar ^{[1
]}

Gurram, Venkata Ramesh Babu ^{[1
]}

Chada, Raji Reddy ^{[1
]}

Burri, David Raju ^{[1
]}

Kamaraju, Seetha Rama Rao ^{[1
]}

机构：

[1] CSIR Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500007, Andhra Pradesh, India

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2018年 / 61卷

关键词：

Biomass; Ethyl levulinate; gamma-Valerolactone; SBA-15; Cobalt; FISCHER-TROPSCH SYNTHESIS; CO/SBA-15; CATALYSTS; MESOPOROUS SILICA; FURFURYL ALCOHOL; FUEL ADDITIVES; ACID; CONVERSION; ESTERS; PLATFORM; HYDROCARBONS;

D O I：

10.1016/j.jiec.2017.12.020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present work is aimed to produce gamma-valerolactone (GVL) from ethyl levulinate hydrogenation over non-noble metal cobalt catalysts at atmospheric pressure in continuous process. Various supported (SBA-15, SiO2, Al2O3, ZrO2, and TiO2) cobalt catalysts were prepared by wet impregnation method and characterized by XRD, N-2 physisorption, SEM, TEM, NH3-TPD, H-2-TPR and H-2-pulse chemisorption techniques. The yield of GVL follows the trend Co/SBA-15 > Co/SiO2 > Co/Al2O3 > Co/ZrO2 > Co/TiO2 similar to trend in active Co metal surface area. The catalytic activity of the supported Co catalyst is strongly influenced by the dispersion and particle size of the Co. (C) 2017 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：227 / 235

页数：9

共 55 条

[1] Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass
Alonso, David Martin
Wettstein, Stephanie G.
Dumesic, James A.
[J]. GREEN CHEMISTRY, 2013, 15 (03) : 584 - 595
[2] [Anonymous], ENERGY FUELS
[3] [Anonymous], GREEN CHEM
[4] [Anonymous], GREEN CHEM
[5] [Anonymous], CATAL SCI TECHNOL
[6] [Anonymous], CATAL SCI TECHNOL
[7] [Anonymous], CHEMSUSCHEM
[8] TEMPERATURE-PROGRAMMED REDUCTION OF COO/AL2O3 CATALYSTS
ARNOLDY, P
MOULIJN, JA
[J]. JOURNAL OF CATALYSIS, 1985, 93 (01) : 38 - 54
[9] Selective Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of a Recyclable Cobalt/SBA-15 Catalyst
Audemar, Maite
Ciotonea, Carmen
Vigier, Karine De Oliveira
Royer, Sebastien
Ungureanu, Adrian
Dragoi, Brindusa
Dumitriu, Emil
Jerome, Francois
[J]. CHEMSUSCHEM, 2015, 8 (11) : 1885 - 1891
[10] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals
Chheda, Juben N.
Huber, George W.
Dumesic, James A.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) : 7164 - 7183

← 1 2 3 4 5 6 →