Synthesis, crystal structure and magnetic property of a novel manganese complex [MnL2(NCS)2] [L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole]

被引：0

作者：

Zhu, DR ^{[1
]}

Wang, TW

Zhong, SL

Xu, Y

You, XZ

机构：

[1] Nanjing Univ Technol, Coll Chem & Chem Engn, Nanjing 210009, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210009, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 05期

关键词：

manganese(II) complex; crystal structure; ESI-MS spectra; triazole;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel manganese(II) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (L), [MnL2(NCS)(2)], has been synthesized and its structure characterized by X-ray crystallography, FT-IR and ESI-MS spectroscopy. In the structure there is an inversion center at the manganese(II) atom which is octahedrally coordinated to four nitrogen atoms from two triaryltriazole ligands (L) and nitrogen atoms of two NCS- ions in a trans arrangement. Magnetic measurements show that the complex is high-spin species in the 75similar to300 K range.

引用

页码：508 / 512

页数：5

共 25 条

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