Synthesis, crystal structure and magnetic property of a novel manganese complex [MnL2(NCS)2] [L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole]

被引：0
|
作者：
Zhu, DR [1 ]
Wang, TW
Zhong, SL
Xu, Y
You, XZ
机构：
[1] Nanjing Univ Technol, Coll Chem & Chem Engn, Nanjing 210009, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210009, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 20卷 / 05期
关键词：
manganese(II) complex; crystal structure; ESI-MS spectra; triazole;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel manganese(II) complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole (L), [MnL2(NCS)(2)], has been synthesized and its structure characterized by X-ray crystallography, FT-IR and ESI-MS spectroscopy. In the structure there is an inversion center at the manganese(II) atom which is octahedrally coordinated to four nitrogen atoms from two triaryltriazole ligands (L) and nitrogen atoms of two NCS- ions in a trans arrangement. Magnetic measurements show that the complex is high-spin species in the 75similar to300 K range.
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页码：508 / 512
页数：5
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