Counterion effect on the phase behavior of perfluoropolyether carboxylates: micelles and liquid crystals in water

被引：29
作者：
Caboi, F
Chittofrati, A
Lazzari, P
Monduzzi, M
机构：
[1] Univ Cagliari, Dipartimento Sci Chim, Cittadella Univ Monserrato, I-09042 Monserrato, Italy
[2] Ausimont CRS, Milan, Italy
来源：
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1999年 / 160卷 / 01期
关键词：
PFPE surfactants; self-assembly; counterion effect; NMR; surface tension; conductivity;
D O I：
10.1016/S0927-7757(99)00260-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Perfluoropolyether carboxylates having sodium, potassium or ammonium counterions, and hydrophobic chains, mostly Cl-C3F6O- terminated, have been investigated in aqueous binary systems, with the focus laid upon the counterion effect on the major self-assembly features. Micellization and liquid crystal formation have been detected via surface tension, conductivity, optical microscopy and NMR. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：47 / 56
页数：10
相关论文
共 22 条
123