Longan seed and peel as environmentally friendly corrosion inhibitor for mild steel in acid solution: Experimental and theoretical studies

被引:145
|
作者
Liao, Liu Li [1 ]
Mo, Shi [1 ]
Luo, Hong Qun [1 ]
Li, Nian Bing [1 ]
机构
[1] Southwest Univ, Sch Chem & Chem Engn, Key Lab Ecoenvironm Gorges Reservoir Reg 3, Minist Educ, Chongqing 400715, Peoples R China
基金
中国国家自然科学基金;
关键词
Mild steel; Electrochemical measurements; Modeling studies; Eco-friendly inhibitor; Longan; 1 M HCL; HYDROCHLORIC-ACID; SULFURIC-ACID; CARBON-STEEL; NACL SOLUTION; EXTRACT; MEDIA; DERIVATIVES; ADSORPTION; COPPER;
D O I
10.1016/j.jcis.2017.03.091
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Longan seed and peel were extracted and used for impeding the corrosion of mild steel in hydrochloric acid solution. Experimental analyses indicate that the water extract of Longan's seed and peel, a mixed type inhibitor, can be chemically adsorbed onto the steel surface, and its inhibition effect rises with increasing extract concentration. To understand the adsorption mechanism and the contributions of the four main compounds of the extract to corrosion protection effect, quantum chemical methods and infrared spectrum were also employed. Theoretically, four main antioxidant compounds were regarded as effective components in the water extract of Longan's seed and peel. (C) 2017 Elsevier Inc. All rights reserved.
引用
收藏
页码:110 / 119
页数:10
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