Preparation and property of polyvinyl alcohol-based film embedded with gold nanoparticles

被引:26
作者
Sun, Changmei [1 ]
Qu, Rongjun [1 ]
Ji, Chunnuan [1 ]
Meng, Yanfeng [1 ]
Wang, Chunhua [1 ]
Sun, Yanzhi [1 ]
Qi, Lingyan [1 ]
机构
[1] Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Peoples R China
关键词
Au nanoparticles; Polyvinyl alcohol; Composite materials; Film; Thermal property; Colloids; SILVER NANOPARTICLES; GREEN METHOD; NANOCOMPOSITE; POLYMER; AG;
D O I
10.1007/s11051-008-9552-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Gold nanoparticles were prepared by a simple heat-treated method using polyvinyl alcohol (PVA) as reducing and stabilizing agent in this article. UV/Vis spectroscopy was used to monitor the preparation. The formation of a sharp band at similar to 530 nm in the UV/Vis spectra and morphological characters revealed by transmission electron microscopy indicated the generation of Au nanoparticles. The PVA film embedded with Au nanoparticles was prepared by flow casting method and characterized by thermogravimetric analysis, differential scanning calorimetry, X-ray diffraction, Fourier transform infrared spectra, and X-ray photoelectron spectroscopy. The results showed that Au nanoparticles embedded in PVA film can improve the thermal stability of the film under investigation, leading to interesting technological applications.
引用
收藏
页码:1005 / 1010
页数:6
相关论文
共 15 条
[1]  
Anastas P., 1998, GREEN CHEM THEORY PR
[2]   Glass transition behavior of alumina/polymethylmethacrylate nanocomposites [J].
Ash, BJ ;
Schadler, LS ;
Siegel, RW .
MATERIALS LETTERS, 2002, 55 (1-2) :83-87
[3]   Characterization, electrical and magnetic properties of PVA films filled with FeCl3-MnCl2 mixed fillers [J].
El-Khodary, A. ;
Oraby, A. H. ;
Abdelnaby, M. M. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (11) :1739-1746
[4]   In-situ formation of Ag-containing nanoparticles in thin polymer films [J].
Fritzsche, W ;
Porwol, H ;
Wiegand, A ;
Bornmann, S ;
Kohler, JM .
NANOSTRUCTURED MATERIALS, 1998, 10 (01) :89-97
[5]   The effect of protein-free versus protein-containing medium on the mechanical properties and uptake of ions of PVA/PVP hydrogels [J].
Fussell, G ;
Thomas, J ;
Scanlon, J ;
Lowman, A ;
Marcolongo, M .
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 2005, 16 (04) :489-503
[6]   POLYMERIZATION IN THE PRESENCE OF SEEDS .4. EMULSION POLYMERS CONTAINING INORGANIC FILLER PARTICLES [J].
HERGETH, WD ;
STEINAU, UJ ;
BITTRICH, HJ ;
SIMON, G ;
SCHMUTZLER, K .
POLYMER, 1989, 30 (02) :254-258
[7]   Synthesis of polysaccharide-stabilized gold and silver nanoparticles: a green method [J].
Huang, HZ ;
Yang, XR .
CARBOHYDRATE RESEARCH, 2004, 339 (15) :2627-2631
[8]   One-step preparation of poly(vinyl alcohol)-protected Pt nanoparticles through a heat-treatment method [J].
Luo, Yonglan ;
Sun, Xuping .
MATERIALS LETTERS, 2007, 61 (10) :2015-2017
[9]   Nanoparticle-embedded polymer: In situ synthesis, free-standing films with highly monodisperse silver nanoparticles and optical limiting [J].
Porel, S ;
Singh, S ;
Harsha, SS ;
Rao, DN ;
Radhakrishnan, TP .
CHEMISTRY OF MATERIALS, 2005, 17 (01) :9-12
[10]   A simple and "green" method for the synthesis of Au, Ag, and Au-Ag alloy nanoparticles [J].
Raveendran, P ;
Fu, J ;
Wallen, SL .
GREEN CHEMISTRY, 2006, 8 (01) :34-38