Enhancing dielectric properties of barium titanate macrofibers

被引:15
作者
Sebastian, T. [1 ]
Michalek, A. [2 ]
Hedayati, M. [1 ,3 ]
Lusiola, T. [1 ]
Clemens, F. [1 ]
机构
[1] Empa Swiss Fed Labs Mat Sci & Technol, Lab High Performance Ceram, Uberlandstr 129, CH-8600 Dubendorf, Switzerland
[2] Fachhsch Munster, Fachbereich Chem Ingn, Stegerwaldstr 39, D-48565 Steinfurt, Germany
[3] Tarbiat Modares Univ, Dept Mat Engn, Fac Engn, Tehran 14115143, Iran
基金
瑞士国家科学基金会;
关键词
Electrospinning; Piezoelectric; Thermoplastic processing; Nanofibers; Macrofibers; BaTiO3; BATIO3; CERAMICS; SINGLE-CRYSTALS; PIEZOELECTRIC PROPERTIES; THERMOPLASTIC EXTRUSION; BEHAVIOR; FIBERS;
D O I
10.1016/j.jeurceramsoc.2019.05.040
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The motivation of this work was to improve the dielectric properties of BaTiO3 (BT) macrofibers by mixing BT nanofibers and commercial BT powder. BT nanofibers were fabricated via electrospinning synthesis. The calcined electrospun nanofibers were chopped and mixed with BT powder and converted in to a thermoplastic feedstock for extrusion of ceramic macrofibers with a diameter of 500 mu m. The electromechanical properties of the BaTiO3 macrofibers were investigated by varying calcination temperature of the nanofibers. For both nano and macro fibers, microstructure and phase composition was investigated by SEM and XRD. It could be observed that an increase in calcination temperature of the nanofibers enhanced the final electromechanical properties of the sintered macrofibers. The relative permittivity increased almost twice, the remanent polarisation increased about 4 times and the strain almost increased 10 times with the addition of calcined nanofibers to macrofibers.
引用
收藏
页码:3716 / 3721
页数:6
相关论文
共 35 条
[1]   BaTiO3-based piezoelectrics: Fundamentals, current status, and perspectives [J].
Acosta, M. ;
Novak, N. ;
Rojas, V. ;
Patel, S. ;
Vaish, R. ;
Koruza, J. ;
Rossetti, G. A., Jr. ;
Roedel, J. .
APPLIED PHYSICS REVIEWS, 2017, 4 (04)
[2]  
AI-Shakarchi E. K., 2011, J MOD PHYS, V2, P9
[3]   TWINNING IN FERROELECTRIC AND FERROELASTIC CERAMICS - STRESS RELIEF [J].
ARLT, G .
JOURNAL OF MATERIALS SCIENCE, 1990, 25 (06) :2655-2666
[4]  
Bach M., 2018, IND ADD MAN P ADD MA
[5]   Novel Characterization Procedure for Single Piezoelectric Fibers [J].
Belloli, Alberto ;
Heiber, Juliane ;
Clemens, Frank ;
Ermanni, Paolo .
JOURNAL OF INTELLIGENT MATERIAL SYSTEMS AND STRUCTURES, 2009, 20 (03) :355-363
[6]   Small and large signal ferroelectric properties of single lead zirconium titanate fibers [J].
Bortolani, Francesca ;
Michen, Marina Ismael ;
Graule, Thomas ;
Clemens, Frank .
JOURNAL OF INTELLIGENT MATERIAL SYSTEMS AND STRUCTURES, 2015, 26 (07) :865-871
[7]   CRYSTAL STABILITY AND THE THEORY OF FERROELECTRICITY [J].
COCHRAN, W .
ADVANCES IN PHYSICS, 1960, 9 (36) :387-423
[8]   Contributions to the piezoelectric effect in ferroelectric single crystals and ceramics [J].
Damjanovic, D .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (10) :2663-2676
[9]   Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics [J].
Fu, HX ;
Cohen, RE .
NATURE, 2000, 403 (6767) :281-283
[10]   Crystallography Open Database - an open-access collection of crystal structures [J].
Grazulis, Saulius ;
Chateigner, Daniel ;
Downs, Robert T. ;
Yokochi, A. F. T. ;
Quiros, Miguel ;
Lutterotti, Luca ;
Manakova, Elena ;
Butkus, Justas ;
Moeck, Peter ;
Le Bail, Armel .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :726-729