Synthesis and Crystal Structure of a Novel Ho(III) Coordination Polymer with Oxalic Acid

被引：0
作者：
Li, Tian-tian [1 ]
Xia, Jun [1 ]
机构：
[1] Tianjin Polytech Univ, Sch Environm & Chem Engn, Tianjin 300387, Peoples R China
来源：
EIGHTH CHINA NATIONAL CONFERENCE ON FUNCTIONAL MATERIALS AND APPLICATIONS | 2014年 / 873卷
关键词：
Holmium(III) complex; Oxalic acid; Crystal structure; METAL-ORGANIC FRAMEWORKS;
D O I：
10.4028/www.scientific.net/AMR.873.697
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A novel metal-organic frameworks (MOFs), {[Ho(ox)(1.5)(H2O)(3)] center dot CH3OH center dot(C2N2H6)(0.5)}n has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR analyses, elemental analysis. The complex crystallizes in the monoclinic system with the P2(1)/c space group. The metal ion is nine-coordinate and connected by oxalate to form 2D honeycomb-like structure.
引用
收藏
页码：697 / 700
页数：4
相关论文
共 21 条
[1]   Luminescent metal-organic frameworks [J].
Allendorf, M. D. ;
Bauer, C. A. ;
Bhakta, R. K. ;
Houk, R. J. T. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1330-1352
[2]   Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules [J].
Chen, Banglin ;
Xiang, Shengchang ;
Qian, Guodong .
ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) :1115-1124
[3]   Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu2+•••I- interactions and modification of the structures and properties of MOFs [J].
Fu, Junhong ;
Li, Huijun ;
Mu, Yajuan ;
Hou, Hongwei ;
Fan, Yaoting .
CHEMICAL COMMUNICATIONS, 2011, 47 (18) :5271-5273
[4]   Lanthanide Germanate Cluster Organic Frameworks Constructed from {Ln8Ge12} or {Ln11Ge12} Cage Cluster Building Blocks [J].
He, Huan ;
Cao, Gao-Juan ;
Zheng, Shou-Tian ;
Yang, Guo-Yu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (43) :15588-+
[5]   Keeping the Ball Rolling: Fullerene-like Molecular Clusters [J].
Kong, Xiang-Jian ;
Long, La-Sheng ;
Zheng, Zhiping ;
Huang, Rong-Bin ;
Zheng, Lan-Sun .
ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (02) :201-209
[6]   Magnetic metal-organic frameworks [J].
Kurmoo, Mohamedally .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1353-1379
[7]   Selective gas adsorption and separation in metal-organic frameworks [J].
Li, Jian-Rong ;
Kuppler, Ryan J. ;
Zhou, Hong-Cai .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1477-1504
[8]   Engineering Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation [J].
Liu, Yan ;
Xuan, Weimin ;
Cui, Yong .
ADVANCED MATERIALS, 2010, 22 (37) :4112-4135
[9]   Lanthanide-doped luminescent ionogels [J].
Lunstroot, Kyra ;
Driesen, Kris ;
Nockemann, Peter ;
Van Hecke, Kristof ;
Van Meervelt, Luc ;
Goerller-Walrand, Christiane ;
Binnemans, Koen ;
Bellayer, Severine ;
Viau, Lydie ;
Le Bideau, Jean ;
Vioux, Andre .
DALTON TRANSACTIONS, 2009, (02) :298-306
[10]   Enantioselective catalysis with homochiral metal-organic frameworks [J].
Ma, Liqing ;
Abney, Carter ;
Lin, Wenbin .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1248-1256
123