Iron-Catalyzed Alkene Hydroboration with Pinacolborane

被引：20

作者：

Lei, Zhang ^{[1
]}

Huang, Zheng ^{[1
]}

机构：

[1] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

SYNLETT | 2013年 / 24卷 / 14期

关键词：

iron; alkene; organoboronate ester; hydroboration; homogeneous catalysis; ETHYLENE POLYMERIZATION CATALYSTS; 2-PI+2-PI CYCLOADDITION; COMPLEXES; HYDROGENATION; LIGANDS;

D O I：

10.1055/s-0033-1339645

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Well-defined iron complexes have been studied intensively as an alternative for precious-metal catalysts in recent years. Here we highlight the opportunities of using iron complexes as catalysts in diene and alkene hydroboration. The iron complexes, supported by suitable ligands, can be superior to precious-metal systems in terms of efficiency and selectivity for alkene hydroborations with pinacolborane.

引用

页码：1745 / 1747

页数：3

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