Propagation of a reaction front accompanied by island formation: CO/Au/Ni(111)

Recent high-pressure scanning tunneling microscopy studies, performed at room temperature, have explicitly demonstrated the specifics of the CO-mediated removal of Ni atoms from the topmost layer of an Au/Ni(111) surface alloy. After an incubation period, the reaction is found to start at step edges. On each edge, a large fraction of Ni atoms is removed from the terrace in certain areas, whereas other areas are nearly intact after a given time. With increasing time, the former areas begin to overlap and the reaction front becomes somewhat more homogeneous. The Au atoms remaining behind the front form nm-sized islands. Here, we present Monte Carlo simulations reproducing all these observations. (c) 2006 Elsevier B.V. All rights reserved.