Oxidative cleavage of vic-diols to aldehydes with dioxygen catalyzed by Ru(PPh3)3Cl2 on active carbon

被引：71

作者：

Takezawa, E ^{[1
]}

Sakaguchi, S ^{[1
]}

Ishii, Y ^{[1
]}

机构：

[1] Kansai Univ, Fac Engn & High Technol, Dept Appl Chem, Res Ctr, Suita, Osaka 5648680, Japan

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 05期

关键词：

D O I：

10.1021/ol990117w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A variety of vic-diols were first successfully cleaved to the corresponding aldehydes with dioxygen catalyzed by RU(PPh3)(3)Cl-2 on active carbon in fair to good yields. For example, treatment of 1,2-octandiol and 1,2-cyclooctanediol with dioxygen in the presence of Ru(PPh3)(3)Cl-2/C in PhCF3 at 60 degrees C for 15 h produced heptanal and 1,8-octanedial in 77% and 76% yields, respectively.

引用

页码：713 / 715

页数：3

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