Bioactive oligomers from natural polyhydroxyalkanoates and their synthetic analogues

被引：8
|
作者：
Adamus, Grazyna [1 ]
Kurcok, Piotr [1 ]
Radecka, Iza [2 ]
Kowalczuk, Marek [1 ,2 ]
机构：
[1] Polish Acad Sci, Ctr Polymer & Carbon Mat, 34 M Curie Sklodowskiej St, PL-41119 Zabrze, Poland
[2] Wolverhampton Univ, Fac Sci & Engn, Sch Biol Chem & Forens Sci, Wolverhampton WV1 1LY, England
来源：
POLIMERY | 2017年 / 62卷 / 04期
关键词：
aliphatic polyester; anionic polymerization; bioactive oligomer; beta-substituted beta-lactone; RING-OPENING POLYMERIZATION; RACEMIC-BETA-BUTYROLACTONE; MOLECULAR-LEVEL STRUCTURE; ANIONIC-POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; MASS-SPECTROMETRY; DELIVERY-SYSTEMS; DEGRADATION; ACID; PHB;
D O I：
10.14314/polimery.2017.317
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Contemporary reports on the bioactive oligomers derived from natural aliphatic co-polyesters (PHA) and their synthetic analogues, formed through anionic ring-opening polymerization (ROP) of beta-substituted beta-lactones are presented. Synthetic routes for such oligomers, developed mostly by Polish authors, are discussed. The described approaches enable design of novel biodegradable and bioactive oligomers for diverse applications in medicine, cosmetic industry and agrochemistry.
引用
收藏
页码：317 / 322
页数：6
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