Bioactive oligomers from natural polyhydroxyalkanoates and their synthetic analogues

被引：8
|
作者：
Adamus, Grazyna [1 ]
Kurcok, Piotr [1 ]
Radecka, Iza [2 ]
Kowalczuk, Marek [1 ,2 ]
机构：
[1] Polish Acad Sci, Ctr Polymer & Carbon Mat, 34 M Curie Sklodowskiej St, PL-41119 Zabrze, Poland
[2] Wolverhampton Univ, Fac Sci & Engn, Sch Biol Chem & Forens Sci, Wolverhampton WV1 1LY, England
来源：
POLIMERY | 2017年 / 62卷 / 04期
关键词：
aliphatic polyester; anionic polymerization; bioactive oligomer; beta-substituted beta-lactone; RING-OPENING POLYMERIZATION; RACEMIC-BETA-BUTYROLACTONE; MOLECULAR-LEVEL STRUCTURE; ANIONIC-POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; MASS-SPECTROMETRY; DELIVERY-SYSTEMS; DEGRADATION; ACID; PHB;
D O I：
10.14314/polimery.2017.317
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Contemporary reports on the bioactive oligomers derived from natural aliphatic co-polyesters (PHA) and their synthetic analogues, formed through anionic ring-opening polymerization (ROP) of beta-substituted beta-lactones are presented. Synthetic routes for such oligomers, developed mostly by Polish authors, are discussed. The described approaches enable design of novel biodegradable and bioactive oligomers for diverse applications in medicine, cosmetic industry and agrochemistry.
引用
收藏
页码：317 / 322
页数：6
相关论文
共 50 条
  • [1] Special Issue: From Natural Polyphenols to Synthetic Bioactive Analogues
    Tringali, Corrado
    MOLECULES, 2020, 25 (12):
  • [2] Modulation of Proteasome Machinery by Natural and Synthetic Analogues of the Marine Bioactive Compound Petrosaspongiolide M
    Margarucci, Luigi
    Tosco, Alessandra
    De Simone, Rosa
    Riccio, Raffaele
    Monti, Maria Chiara
    Casapullo, Agostino
    CHEMBIOCHEM, 2012, 13 (07) : 982 - 986
  • [3] Synthetic, semisynthetic and natural analogues of peloruside A
    Brackovic, Amira
    Harvey, Joanne E.
    CHEMICAL COMMUNICATIONS, 2015, 51 (23) : 4750 - 4765
  • [4] NATURAL YTTRIALITE AND ITS SYNTHETIC ANALOGUES
    BATALIEV.NG
    KRIVOKON.GK
    BONDAR, IA
    SIDORENK.GA
    DOKLADY AKADEMII NAUK SSSR, 1969, 189 (03): : 615 - &
  • [5] Natural and Synthetic Capsaicin Analogues: A Comprehensive
    Borges, Lara Gimenez
    Alves, Thais Nascimento de Oliveira
    Vassiliades, Sandra Valeria
    Parise-Filho, Roberto
    CURRENT MEDICINAL CHEMISTRY, 2024,
  • [6] SYNTHETIC AND MODIFIED NATURAL BIOACTIVE MACROMOLECULES
    CARRAHER, CE
    GEBELEIN, CG
    FOSTER, V
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 6 - PMSE
  • [7] Biosynthesis, properties and potential of natural–synthetic hybrids of polyhydroxyalkanoates and polyethylene glycols
    L. John R. Foster
    Applied Microbiology and Biotechnology, 2007, 75 : 1241 - 1247
  • [8] Synthetic Glycopolypeptides as Biomimetic Analogues of Natural Glycoproteins
    Bonduelle, Colin
    Lecommandoux, Sebastien
    BIOMACROMOLECULES, 2013, 14 (09) : 2973 - 2983
  • [9] An efficient synthetic scheme for natural α-conotoxins and their analogues
    Zhmak, MN
    Kasheverov, IE
    Utkin, YN
    Tsetlin, VI
    Vol'pina, OM
    Ivanov, VT
    RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY, 2001, 27 (02) : 67 - 71
  • [10] Canadensenes: Natural and semi-synthetic analogues
    Shi, OW
    Nikolakakis, A
    Sauriol, F
    Mamer, O
    Zamir, LO
    CANADIAN JOURNAL OF CHEMISTRY, 2003, 81 (05) : 406 - 411
12345