Old Molecule, New Chemistry: Exploring Silicon Phthalocyanines as Emerging N-Type Materials in Organic Electronics

被引：18

作者：

Yutronkie, Nathan J. ^{[1
]}

Grant, Trevor M. ^{[2
]}

Melville, Owen A. ^{[2
]}

Lessard, Benoit H. ^{[2
]}

Brusso, Jaclyn L. ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem & Biomol Sci, 150 Louis Pasteur, Ottawa, ON K1N 6N5, Canada

[2] Univ Ottawa, Dept Chem & Biol Engn, 161 Louis Pasteur, Ottawa, ON K1N 6N5, Canada

来源：

MATERIALS | 2019年 / 12卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

silicon phthalocyanines; n-type organic semiconductors; organic thin-film transistors; SEMICONDUCTORS; CONVENIENT;

D O I：

10.3390/ma12081334

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient synthesis of silicon phthalocyanines (SiPc) eliminating the strenuous reaction conditions and hazardous reagents required by classical methods is described. Implementation into organic thin-film transistors (OTFTs) affords average electron field-effect mobility of 3.1 x 10(-3) cm(2) V-1 s(-1) and threshold voltage of 25.6 V for all synthetic routes. These results demonstrate that our novel chemistry can lead to high performing SiPc-based n-type OTFTs.

引用

页数：8

共 34 条

[1] A convenient way to generate hydrogen chloride in the freshman lab [J].

Arnaiz, FJ .

JOURNAL OF CHEMICAL EDUCATION, 1995, 72 (12) :1139-1139

[2] Phthalocyanines Part VII Phthalocyanine as a co-ordinating group - A general investigation of the Metallic derivatives [J].

Barrett, PA ;

Dent, CE ;

Linstead, RP .

JOURNAL OF THE CHEMICAL SOCIETY, 1936, :1719-1736

[3]

Bian Y., 2015, RECENT ADV PHTHALOCY, V172, P159

[4] PREPARATION OF N,N,N'-TRIS(TRIMETHYLSILYL)AMIDINES - A CONVENIENT ROUTE TO UNSUBSTITUTED AMIDINES [J].

BOERE, RT ;

OAKLEY, RT ;

REED, RW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 331 (02) :161-167

[5] The phthalocyanines - A new class of synthetic pigments, and dyes [J].

Dahlen, MA .

INDUSTRIAL AND ENGINEERING CHEMISTRY, 1939, 31 :839-847

[6] Bis(tri-n-alkylsilyl oxide) silicon phthalocyanines: a start to establishing a structure property relationship as both ternary additives and non-fullerene electron acceptors in bulk heterojunction organic photovoltaic devices [J].

Dang, Minh-Trung ;

Grant, Trevor M. ;

Yan, Han ;

Seferos, Dwight S. ;

Lessard, Benoit H. ;

Bender, Timothy P. .

JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (24) :12168-12182

[7] Phthalocyanines and related compounds: organic targets for nonlinear optical applications [J].

de la Torre, G ;

Vazquez, P ;

Agullo-Lopez, F ;

Torres, T .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (08) :1671-1683

[8] CONJUGATED MACROCYCLES .28. ADDUCTS FROM DIIMINOISOINDOLINE AND ARYLENE-M-DIAMINES, AND A NEW TYPE OF CROSS-CONJUGATED MACROCYCLE WITH 3-QUARTERS OF THE CHROMOPHORE OF PHTHALOCYANINE [J].

ELVIDGE, JA ;

GOLDEN, JH .

JOURNAL OF THE CHEMICAL SOCIETY, 1957, (FEB) :700-709

[9] Multifunctional ternary additive in bulk heterojunction OPV: increased device performance and stability [J].

Grant, Trevor M. ;

Gorisse, Therese ;

Dautel, Olivier ;

Wantz, Guillaume ;

Lessard, Benoit H. .

JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (04) :1581-1587

[10] Selective Dye Loading at the Heterojunction in Polymer/Fullerene Solar Cells [J].

Honda, Satoshi ;

Ohkita, Hideo ;

Benten, Hiroaki ;

Ito, Shinzaburo .

ADVANCED ENERGY MATERIALS, 2011, 1 (04) :588-598

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