Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals

被引：1539

作者：

Benelli, C ^{[1
]}

Gatteschi, D ^{[1
]}

机构：

[1] Univ Florence, Polo Sci Univ, UdR INSTM, Dept Chem, I-50019 Sesto Fiorentino, Italy

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 06期

关键词：

D O I：

10.1021/cr010303r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The understanding of the magnetic interactions involving rare-earth ions in molecular magnets is still far from being satisfactory. The key point is the role of the orbital contribution, which introduces many complications, in particular large magnetic anisotropies. It is necessary to gather a large number of experimental data, and isotropic measurements are not particularly well suited in order to obtain the information which is needed to reconstruct the full map of the magnetic interactions.

引用

页码：2369 / 2387

页数：19

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