A New Route to Substituted Phenols by Cationic Rhodium(I)/BINAP Complex-Catalyzed Decarboxylative [2+2+2] Cycloaddition

被引：70
作者：
Hara, Hiromi [1 ]
Hirano, Masao [1 ]
Tanaka, Ken [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Dept Appl Chem, Koganei, Tokyo 1848588, Japan
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 06期
关键词：
REGIOSELECTIVE INTERMOLECULAR CYCLOTRIMERIZATION; ENANTIOSELECTIVE SYNTHESIS; TERMINAL ALKYNES; CONSTRUCTION; ALPHA; OMEGA-DIYNES; CYCLOHEXADIENES; DERIVATIVES; 1,6-DIYNES; MONOYNES; DIYNES;
D O I：
10.1021/ol900123d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new route to substituted phenols has been developed by cationic rhodium(I)/BINAP complex-catalyzed decarboxylative [2 + 2 + 2] cycloadditions of 1,6- and 1,7-diynes with commercially available vinylene carbonate.
引用
收藏
页码：1337 / 1340
页数：4
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