Kinetics of carbon multi-wall nanotube synthesis by catalytic pyrolysis of methane

被引：0
|
作者：
Rakov, EG [1 ]
Ivanov, IG [1 ]
Blinov, SN [1 ]
Kazakov, NV [1 ]
Skudin, VV [1 ]
Digurov, NG [1 ]
Bogdanovich, AK [1 ]
机构：
[1] DI Mendeleev Univ Chem Technol Inst, Dept Nanotechnol, Moscow 125047, Russia
来源：
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2004年 / 12卷 / 1-2期
基金：
俄罗斯基础研究基金会;
关键词：
nanotubes; nanofibers; methane; catalytic pyrolysis;
D O I：
10.1081/FST-120027129
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
By method of isothermal gravimetry at 600-700 C, CH4 concentration 32-100% in Ar and 91-100% in H-2 under atmospheric pressure the kinetics of CH4 pyrolysis under Ni/La2O3 catalysts is studied. Estimated apparent activation energy of reaction is 73 kJ/mol for fresh catalyst and 71 kJ/mol for aged one. The reaction order on CH4 changes from 1.05 at 600degreesC to 1.3 at 700degreesC. The influence of H-2 concentration on the reaction rate is more complicated. On the basis of kinetics measurements continuously working laboratory-scale reactor with gas and catalyst counter-flow is constructed and tested.
引用
收藏
页码：29 / 32
页数：4
相关论文
共 50 条
  • [1] Synthesis of multi-wall carbon nanotubes by simple pyrolysis
    Mahanundia, P.
    Vishwakarma, P. N.
    Nanda, K. K.
    Prasad, V.
    Barai, K.
    Mondal, A. K.
    Sarangi, S.
    Dey, G. K.
    Subramanyam, S. V.
    SOLID STATE COMMUNICATIONS, 2008, 145 (03) : 143 - 148
  • [2] Synthesis of platinum/multi-wall carbon nanotube catalysts
    Mu P.
    Haolin T.
    Shichun M.
    Runzhang Y.
    Journal of Materials Research, 2004, 19 (8) : 2279 - 2284
  • [3] Synthesis of platinum/multi-wall carbon nanotube catalysts
    Pan, M
    Tang, HL
    Mu, SC
    Yuan, RZ
    JOURNAL OF MATERIALS RESEARCH, 2004, 19 (08) : 2279 - 2284
  • [4] Carbon nanotube prepared by catalytic pyrolysis of methane
    Chen, P
    Wang, PF
    Lin, GD
    Zhang, HB
    Tsai, KR
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1995, 16 (11): : 1783 - 1784
  • [5] Nanotube buckling in aligned multi-wall carbon nanotube composites
    Thostenson, ET
    Chou, TW
    CARBON, 2004, 42 (14) : 3015 - 3018
  • [6] Isotactic and syndiotactic polypropylene/multi-wall carbon nanotube composites: synthesis and properties
    Kovalchuk, Anton A.
    Shevchenko, Vitaliy G.
    Shchegolikhin, Alexander N.
    Nedorezova, Polina M.
    Klyamkina, Alla N.
    Aladyshev, Alexander M.
    JOURNAL OF MATERIALS SCIENCE, 2008, 43 (22) : 7132 - 7140
  • [7] Isotactic and syndiotactic polypropylene/multi-wall carbon nanotube composites: synthesis and properties
    Anton A. Kovalchuk
    Vitaliy G. Shevchenko
    Alexander N. Shchegolikhin
    Polina M. Nedorezova
    Alla N. Klyamkina
    Alexander M. Aladyshev
    Journal of Materials Science, 2008, 43 : 7132 - 7140
  • [8] Microwave Characterization of a Single Multi-Wall Carbon Nanotube
    Katsounaros, A.
    Zhang, J.
    Hao, Y.
    2012 INTERNATIONAL CONFERENCE ON ELECTROMAGNETICS IN ADVANCED APPLICATIONS (ICEAA), 2012, : 591 - 594
  • [9] Shielding effectiveness of multi-wall carbon nanotube composite
    Chang, CM
    Wu, TL
    Chiu, JC
    Lin, CW
    Jou, WS
    Cheng, WH
    2005 IEEE LEOS ANNUAL MEETING CONFERENCE PROCEEDINGS (LEOS), 2005, : 508 - 509
  • [10] A multi-wall carbon nanotube tower electrochemical actuator
    Yun, Y
    Shanov, V
    Tu, Y
    Schulz, MJ
    Yarmolenko, S
    Neralla, S
    Sankar, J
    Subramaniam, S
    NANO LETTERS, 2006, 6 (04) : 689 - 693
12345