Bis[2-(3,5-dimethylpyrazol-1-yl)ethyl]amine-κ3N,N′,N"}chloropalladium(II) chloride dihydrate

被引：3

作者：

de los Angeles Mendoza, Maria

Bernes, Sylvain

Mendoza-Diaz, Guillermo

机构：

[1] Univ Guanajuato, Fac Quim, Guanajuato 36050, Gto, Mexico

[2] UANL, DEP Fac Ciencias Quim, Monterrey 64570, NL, Mexico

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷

关键词：

D O I：

10.1107/S1600536806041985

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [PdCl(C14H23N5)]Cl center dot 2H(2)O, contains a four-coordinate palladium complex, in which the planes of the pyrazole rings are almost perpendicular. This is mainly a consequence of the close steric contacts between the methyl groups which would occur in the case of mirror symmetry, which are avoided by adopting a quasi-twofold rotation symmetry.

引用

页码：M2934 / M2936

页数：3

共 5 条

[1]

Macrae CF, 2006, J APPL CRYSTALLOGR, V39, P453, DOI 10.1107/S0021 88980600731X

[2] Synthesis of new palladium(II) complexes containing hemilabile N-(alkylamino)pyrazole ligands:: Spectroscopic analysis and crystal structure of [PdCl(ddae)]Cl•H2O {ddae = bis[2-(3,5-dimethyl-1-pyrazolyl)ethyl]ethylamine} [J].