Crosslinking in phenylethynyl-terminated polyimides

被引:24
作者
Hinkley, JA [1 ]
Jensen, BJ [1 ]
机构
[1] NASA,LANGLEY RES CTR,COMPOSITES & POLYMERS BRANCH,HAMPTON,VA 23681
关键词
D O I
10.1088/0954-0083/8/4/008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Stress relaxation of cured phenylethynyl-terminated polyimides was used to estimate their equilibrium rubbery moduli. The corresponding concentrations of elastically effective chains derived from classical rubber elasticity theory were less than one-fifth what would be expected if every chain end participated in a crosslink. A model is proposed to allow the calculation of the average crosslink functionalities.
引用
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页码:599 / 605
页数:7
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