Enhanced power conversion efficiency of inverted organic solar cells by using solution processed Sn-doped TiO2 as an electron transport layer

被引:22
作者
Thambidurai, M. [1 ]
Kim, Jun Young [1 ]
Song, Hyung-jun [1 ]
Ko, Youngjun [1 ]
Muthukumarasamy, N. [2 ]
Velauthapillai, Dhayalan [3 ]
Bergmann, Victor W. [4 ]
Weber, Stefan A. L. [4 ]
Lee, Changhee [1 ]
机构
[1] Seoul Natl Univ, Global Frontier Ctr Multiscale Energy Syst, Dept Elect & Comp Engn, Seoul 151744, South Korea
[2] Coimbatore Inst Technol, Dept Phys, Coimbatore 641014, Tamil Nadu, India
[3] Univ Coll Bergen, Dept Engn, Bergen, Norway
[4] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
基金
新加坡国家研究基金会;
关键词
POLYMER PHOTOVOLTAIC CELLS; THIN-FILMS; PERFORMANCE; ZNO; DEPOSITION; DEVICE; WATER; MOO3;
D O I
10.1039/c4ta00531g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have investigated the photovoltaic properties of inverted solar cells comprising a bulk heterojunction film of thieno[3,4-b]-thiophene/benzodithiophene (PTB7) and [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM), sandwiched between indium tin oxide (ITO)/Sn-doped TiO2 front and MoO3/aluminum back electrodes. The inverted organic solar cell (IOSC) fabricated with a Sn-doped TiO2 film showed a significantly greater power conversion efficiency of 7.59%, compared to that of the TiO2 film (6.70%). Further studies confirm that the improved morphology and electrical properties of the Sn-doped TiO2 film result in reduced shunt loss and interfacial charge recombination and hence enhanced photovoltaic performance.
引用
收藏
页码:11426 / 11431
页数:6
相关论文
共 30 条
[1]   Analysis of visible-light-active Sn(II)-TiO2 photocatalysts [J].
Boppana, Venkata Bharat Ram ;
Jiao, Feng ;
Newby, Dave, Jr. ;
Laverock, Jude ;
Smith, Kevin E. ;
Jumas, Jean Claude ;
Hutchings, Greg ;
Lobo, Raul F. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (17) :6185-6189
[2]  
Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO
[3]  
2-A
[4]   ANOMALOUS OPTICAL ABSORPTION LIMIT IN INSB [J].
BURSTEIN, E .
PHYSICAL REVIEW, 1954, 93 (03) :632-633
[5]   High-Performance and Highly Durable Inverted Organic Photovoltaics Embedding Solution-Processable Vanadium Oxides as an Interfacial Hole-Transporting Layer [J].
Chen, Chih-Ping ;
Chen, Yeu-Ding ;
Chuang, Shih-Ching .
ADVANCED MATERIALS, 2011, 23 (33) :3859-+
[6]   High-performance organic thin-film transistors with metal oxide/metal bilayer electrode [J].
Chu, CW ;
Li, SH ;
Chen, CW ;
Shrotriya, V ;
Yang, Y .
APPLIED PHYSICS LETTERS, 2005, 87 (19) :1-3
[7]   Conjugated polymer photovoltaic cells [J].
Coakley, KM ;
McGehee, MD .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4533-4542
[8]   Solution-Processed MoO3 Thin Films As a Hole-Injection Layer for Organic Solar Cells [J].
Girotto, Claudio ;
Voroshazi, Eszter ;
Cheyns, David ;
Heremans, Paul ;
Rand, Barry P. .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (09) :3244-3247
[9]   Conjugated polymer-based organic solar cells [J].
Guenes, Serap ;
Neugebauer, Helmut ;
Sariciftci, Niyazi Serdar .
CHEMICAL REVIEWS, 2007, 107 (04) :1324-1338
[10]   Anode Interfacial Tuning via Electron-Blocking/Hole-Transport Layers and Indium Tin Oxide Surface Treatment in Bulk-Heterojunction Organic Photovoltaic Cells [J].
Hains, Alexander W. ;
Liu, Jun ;
Martinson, Alex B. F. ;
Irwin, Michael D. ;
Marks, Tobin J. .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (04) :595-606