Unique Reactivity of Fluorinated Molecules with Transition Metals

被引：13

作者：

Catalan, Silvia ^{[1
,2
]}

Munoz, Socrates B. ^{[3
]}

Fustero, Santos ^{[1
,2
]}

机构：

[1] Univ Valencia, Dept Quim Organ, E-46100 Burjassot, Spain

[2] Ctr Invest Principe Felipe, Lab Mol Organ, E-46012 Valencia, Spain

[3] Univ So Calif, Loker Hydrocarbon Res Inst, Dept Chem, Los Angeles, CA 90089 USA

来源：

CHIMIA | 2014年 / 68卷 / 06期

关键词：

Catalysis; Copper; Cross coupling; Fluorine; Gold; Metathesis; Pauson-Khand reaction; Silver; Transition metal; ARYL BORONIC ACIDS; SILVER-MEDIATED TRIFLUOROMETHYLATION; CATALYZED OLEFINIC TRIFLUOROMETHYLATION; HYPERVALENT IODINE REAGENTS; C-H TRIFLUOROMETHYLATION; FLUOROFORM-DERIVED CUCF3; RING-CLOSING METATHESIS; BICYCLIC AMINO ESTERS; FREE-RADICAL ADDITION; AZA-MICHAEL REACTION;

D O I：

10.2533/chimia.2014.382

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organofluorine and organometallic chemistry by themselves constitute two potent areas in organic synthesis. Thus, the combination of both offers many chemical possibilities and represents a powerful tool for the design and development of new synthetic methodologies leading to diverse molecular structures in an efficient manner. Given the importance of the selective introduction of fluorine atoms into organic molecules and the effectiveness of transition metals in C C and C-heteroatom bond formation, this review represents an interesting read for this aim.

引用

页码：382 / 409

页数：28

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