Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions

被引：22
|
作者：
Itazaki, Masumi [1 ]
Nakazawa, Hiroshi [1 ]
机构：
[1] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, 3-3-138 Sugimoto, Osaka 5588585, Japan
来源：
IRON CATALYSIS II | 2015年 / 50卷
关键词：
Catalyst; Iron; Cross-dehydrogenative coupling; Oxidant; Radical; C-H BOND; N-SULFONYL ALDIMINES; STUDIEN ZUM ABLAUF; CDC REACTION; HETEROAROMATIC BASES; ACTIVATION; ALKYLATION; SUBSTITUTIONS; ARYLATION; COMPLEX;
D O I：
10.1007/3418_2015_105
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cross-dehydrogenative-coupling (CDC) reactions involving C-H bond activation are powerful tools for C-C bond formation and are highly significant from the perspective of atom economy. A variety of carbon-carbon bond-forming reactions utilizing various coupling partners are known today. Iron-catalyzed organic syntheses have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. This chapter summarizes the development of iron-catalyzed CDC reactions, the reaction mechanism, and the role of the Fe species in the catalytic cycle in the period from 2007 to 2014.
引用
收藏
页码：47 / 81
页数：35
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