Mesoporous carbon derived from vitamin B12:a high-performance bifunctional catalyst for imine formation

被引：50

作者：

Chen, Bo ^{[1
,2
]}

Shang, Sensen ^{[1
,2
]}

Wang, Lianyue ^{[1
]}

Zhang, Yi ^{[1
]}

Gao, Shuang ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 03期

基金：

中国国家自然科学基金;

关键词：

N-DOPED CARBON; AEROBIC OXIDATION; PRIMARY AMINES; SELECTIVE OXIDATION; GRAPHENE OXIDE; ALCOHOLS; EFFICIENT; SYSTEM; CONVENIENT; NANOTUBES;

D O I：

10.1039/c5cc06179b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mesoporous carbon derived from natural vitamin B-12 is applied for the first time in organic synthesis and exhibits exceptionally high dual activity for imine formation via the cross-coupling of alcohols with amines and the self-coupling of primary amines using molecular oxygen or air as the terminal oxidant.

引用

页码：481 / 484

页数：4

共 60 条

[1] Convenient and Mild Epoxidation of Alkenes Using Heterogeneous Cobalt Oxide Catalysts** [J].

Banerjee, Debasis ;

Jagadeesh, Rajenahally V. ;

Junge, Kathrin ;

Pohl, Marga-Martina ;

Radnik, Joerg ;

Brueckner, Angelika ;

Beller, Matthias .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (17) :4359-4363

[2] Aerobic Oxidation of Amines to Imines by Cesium-Promoted Mesoporous Manganese Oxide [J].

Biswas, Sourav ;

Dutta, Biswanath ;

Mullick, Kankana ;

Kuo, Chung-Hao ;

Poyraz, Altug S. ;

Suib, Steven L. .

ACS CATALYSIS, 2015, 5 (07) :4394-4403

[3] Metal-Free and Solvent-Free Oxidative Coupling of Amines to Imines with Mesoporous Carbon from Macrocyclic Compounds [J].

Chen, Bo ;

Wang, Lianyue ;

Dai, Wen ;

Shang, Sensen ;

Lv, Ying ;

Gao, Shuang .

ACS CATALYSIS, 2015, 5 (05) :2788-2794

[4] Direct imine formation by oxidative coupling of alcohols and amines using supported manganese oxides under an air atmosphere [J].

Chen, Bo ;

Li, Jun ;

Dai, Wen ;

Wang, Lianyue ;

Gao, Shuang .

GREEN CHEMISTRY, 2014, 16 (06) :3328-3334

[5] Aerobic Oxidation of Hydroxymethylfurfural and Furfural by Using Heterogeneous CoxOy-N@C Catalysts [J].

Deng, Jin ;

Song, Hai-Jie ;

Cui, Min-Shu ;

Du, Yi-Ping ;

Fu, Yao .

CHEMSUSCHEM, 2014, 7 (12) :3334-3340

[6] Carbocatalysis: Heterogeneous carbons finding utility in synthetic chemistry [J].

Dreyer, Daniel R. ;

Bielawski, Christopher W. .

CHEMICAL SCIENCE, 2011, 2 (07) :1233-1240

[7] Graphene Oxide: A Convenient Carbocatalyst for Facilitating Oxidation and Hydration Reactions [J].

Dreyer, Daniel R. ;

Jia, Hong-Peng ;

Bielawski, Christopher W. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) :6813-6816

[8] Selective Amine Oxidation Using Nb2O5 Photocatalyst and O2 [J].

Furukawa, Shinya ;

Ohno, Yasuhiro ;

Shishido, Tetsuya ;

Teramura, Kentaro ;

Tanaka, Tsunehiro .

ACS CATALYSIS, 2011, 1 (10) :1150-1153

[9] Nitrogen-Doped sp2-Hybridized Carbon as a Superior Catalyst for Selective Oxidation [J].

Gao, Yongjun ;

Hu, Gang ;

Zhong, Jun ;

Shi, Zujin ;

Zhu, Yuanshuai ;

Su, Dang Sheng ;

Wang, Jianguo ;

Bao, Xinhe ;

Ma, Ding .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (07) :2109-2113

[10] Highly dispersed iron oxides on mesoporous carbon for selective oxidation of benzyl alcohol with molecular oxygen [J].

Geng, Longlong ;

Zhang, Xiuyan ;

Zhang, Wenxiang ;

Jia, Mingjun ;

Liu, Gang .

CHEMICAL COMMUNICATIONS, 2014, 50 (22) :2965-2967

← 1 2 3 4 5 6 →