Misoriented domain formation in 6H-SiC single crystal

被引:3
作者
Chen, Bo-Yuan [1 ,2 ]
Liu, Xi [1 ,2 ]
Chen, Zhi-Zhan [1 ]
Chang, Shao-Hui [1 ,2 ]
Xiao, Bing [1 ]
Shi, Er-Wei [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
基金
上海市自然科学基金;
关键词
Computer simulation; Defects; Single crystal growth; Semiconducting materials; SEEDED SUBLIMATION GROWTH; SILICON-CARBIDE; 4H-SIC CRYSTALS; POLYTYPES; BOULES; 6H;
D O I
10.1016/j.jcrysgro.2009.05.013
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
6H-SiC single crystals were grown by the physical vapor transport (PVT) technique. Misoriented domains (MDs) were observed in as-grown crystals. Raman spectra and X-ray diffraction indicated that the MDs are 4H polytype with either (1 0 (1) over bar 2) or (1 0 (1) over bar 6) growth plane. Formation probability of MDs increased continuously as the thermal insulator had been repeatedly used. Simulations based on heat transfer demonstrated that the changes of the temperature and the temperature axial gradient at the center of the growth front were responsible for the phenomenon. The formation mechanism was put forward in terms of atomic structure of various crystal planes. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:3573 / 3576
页数:4
相关论文
共 19 条
[1]   Silicon carbide for microwave power applications [J].
Brylinski, C .
DIAMOND AND RELATED MATERIALS, 1997, 6 (10) :1405-1413
[2]   Status of silicon carbide (SiC) as a wide-bandgap semiconductor for high-temperature applications: A review [J].
Casady, JB ;
Johnson, RW .
SOLID-STATE ELECTRONICS, 1996, 39 (10) :1409-1422
[3]   4H polytype grain formation in PVT-grown 6H-SiC ingots [J].
Fujimoto, T ;
Katsuno, M ;
Ohtani, N ;
Aigo, T ;
Yashiro, H .
SILICON CARBIDE AND RELATED MATERIALS 2001, PTS 1 AND 2, PROCEEDINGS, 2002, 389-3 :47-50
[4]   Growth and characterization of large diameter 6H and 4H SiC single crystals [J].
Gupta, A. ;
Semenas, E. ;
Emorhokpor, E. ;
Chen, J. ;
Zwieback, I. ;
Souzis, A. ;
Anderson, T. .
Silicon Carbide and Related Materials 2005, Pts 1 and 2, 2006, 527-529 :43-46
[5]   CONTROLLED SUBLIMATION GROWTH OF SINGLE CRYSTALLINE 4H-SIC AND 6H-SIC AND IDENTIFICATION OF POLYTYPES BY X-RAY-DIFFRACTION [J].
KANAYA, M ;
TAKAHASHI, J ;
FUJIWARA, Y ;
MORITANI, A .
APPLIED PHYSICS LETTERS, 1991, 58 (01) :56-58
[6]   Effects of graphitization of the crucible on silicon carbide crystal growth [J].
Liu, Xi ;
Shi, Er-Wei ;
Song, Li-Xin ;
Chen, Zhi-Zhan .
JOURNAL OF CRYSTAL GROWTH, 2008, 310 (19) :4314-4318
[7]   Growth of Crack-free 100mm-diameter 4H-SiC Crystals with Low Micropipe Densities [J].
Nakabayashi, M. ;
Fujimoto, T. ;
Katsuno, M. ;
Ohtani, N. ;
Tsuge, H. ;
Yashiro, H. ;
Aigo, T. ;
Hoshino, T. ;
Hirano, H. ;
Tatsumi, K. .
SILICON CARBIDE AND RELATED MATERIALS 2007, PTS 1 AND 2, 2009, 600-603 :3-6
[8]  
Nakashima S, 1997, PHYS STATUS SOLIDI A, V162, P39, DOI 10.1002/1521-396X(199707)162:1<39::AID-PSSA39>3.0.CO
[9]  
2-L
[10]   Polarity- and orientation-related defect distribution in 4H-SiC single crystals [J].
Rost, HJ ;
Schmidbauer, M ;
Siche, D ;
Fornari, R .
JOURNAL OF CRYSTAL GROWTH, 2006, 290 (01) :137-143